Pulse Radiolysis at High Temperatures and High Pressures

H. Christensen, Knud Sehested

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    A cell for pulse radiolytic measurements up to temperatures of 320°C and pressures of 14 MPa is constructed. The activation energy of the reaction OH + Cu2+ is determined to 13.3 kJ × mol−1 (3.2 kcal × mol−1). A preliminary study of the reaction e−aq + e−aq yields an activation energy of 22 kJ × mol−1 (5.3 kcal × mol−1).
    Original languageEnglish
    JournalRadiation Physics and Chemistry
    Volume16
    Issue number2
    Pages (from-to)183-186
    ISSN0969-806X
    DOIs
    Publication statusPublished - 1980

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