Protonic titanate derived from CsxTi2-x/2Mgx/2O4 (x=0.7) with lepidocrocite- type layered structure

Tao Gao, Helmer Fjellvåg, Poul Norby

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Abstract

A layered titanate CsxTi2-x/2Mgx/2O4 (x = 0.7) with lepidocrocite (gamma-FeOOH)-type layered structure was prepared via solid-state reaction. Extraction of both Mg2+ ions in the host layers and interlayer Cs+ ions was achieved during an acid-exchange process, producing a new protonic titanate HxTi2-x/2O4-x/2 center dot H2O. This phase was distinguished from isomorphous related compounds in terms of removable lattice Mg and O atoms. The protonic titanate HxTi2-x/2O4-x/2 center dot H2O showed excellent exfoliation/delamination reactivity upon intercalating organic amine ions as well as the ability to produce single two-dimensional titanate nanosheets with small thickness of about 1 nm. These findings offered a new clue for understanding the physicochemical properties of lattice dopants in lepidocrocite titanates.
Original languageEnglish
JournalJournal of Materials Chemistry
Volume19
Issue number6
Pages (from-to)787-794
ISSN0959-9428
DOIs
Publication statusPublished - 2009
Externally publishedYes

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