Potential energy surfaces of short polyenes in the state T1: Analysis of time resolved resonance Raman spectra

G. Orlandi; F. Negri; R. Wilbrandt; F.W. Langkilde; A.M. Brouwer

doi:10.1016/0010-8545(93)85026-Z

Potential energy surfaces of short polyenes in the state T₁: Analysis of time resolved resonance Raman spectra

G. Orlandi, F. Negri, R. Wilbrandt, F.W. Langkilde, A.M. Brouwer

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The analysis of T₁ resonance Raman spectra of some conjugated compounds is discussed making use of semiempirical quantum chemical calculations. Information obtained about T₁ potential energy curve indicates that in short polyenes the perpendicular form is roughly degenerate with the trans isomer. Preliminary ab initio results on the T₁ vibrational force field of these compounds are reported.

Original language	English
Journal	Coordination Chemistry Reviews
Volume	125
Issue number	1-2
Pages (from-to)	293-300
ISSN	0010-8545
DOIs	https://doi.org/10.1016/0010-8545(93)85026-Z
Publication status	Published - 1993

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title = "Potential energy surfaces of short polyenes in the state T1: Analysis of time resolved resonance Raman spectra",

abstract = "The analysis of T1 resonance Raman spectra of some conjugated compounds is discussed making use of semiempirical quantum chemical calculations. Information obtained about T1 potential energy curve indicates that in short polyenes the perpendicular form is roughly degenerate with the trans isomer. Preliminary ab initio results on the T1 vibrational force field of these compounds are reported.",

keywords = "Vurdering og begr{\ae}nsning af industrielle milj{\o}belastninger",

author = "G. Orlandi and F. Negri and R. Wilbrandt and F.W. Langkilde and A.M. Brouwer",

year = "1993",

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pages = "293--300",

journal = "Coordination Chemistry Reviews",

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T1 - Potential energy surfaces of short polyenes in the state T1: Analysis of time resolved resonance Raman spectra

AU - Orlandi, G.

AU - Negri, F.

AU - Wilbrandt, R.

AU - Langkilde, F.W.

AU - Brouwer, A.M.

PY - 1993

Y1 - 1993

N2 - The analysis of T1 resonance Raman spectra of some conjugated compounds is discussed making use of semiempirical quantum chemical calculations. Information obtained about T1 potential energy curve indicates that in short polyenes the perpendicular form is roughly degenerate with the trans isomer. Preliminary ab initio results on the T1 vibrational force field of these compounds are reported.

AB - The analysis of T1 resonance Raman spectra of some conjugated compounds is discussed making use of semiempirical quantum chemical calculations. Information obtained about T1 potential energy curve indicates that in short polyenes the perpendicular form is roughly degenerate with the trans isomer. Preliminary ab initio results on the T1 vibrational force field of these compounds are reported.

KW - Vurdering og begrænsning af industrielle miljøbelastninger

U2 - 10.1016/0010-8545(93)85026-Z

DO - 10.1016/0010-8545(93)85026-Z

M3 - Journal article

SN - 0010-8545

VL - 125

SP - 293

EP - 300

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

IS - 1-2