Abstract
The polymorphism and polymerisation of two related acids have been investigated under high pressure conditions. Acrylic acid crystallises as a new polymorph at 0.65 GPa whilst methacrylic acid crystallises in a new polymorph at a higher pressure of 1.5 GPa. Both these new polymorphs exhibit similar hydrogen bonding motifs to the low temperature phases, however, the molecular packing differs significantly.
| Original language | English |
|---|---|
| Journal | CrystEngComm |
| Volume | 13 |
| Issue number | 14 |
| Pages (from-to) | 4503-4507 |
| ISSN | 1466-8033 |
| DOIs | |
| Publication status | Published - 2011 |
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