Plasmons on the edge of MoS2 nanostructures

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Abstract

Using ab initio calculations we predict the existence of one-dimensional (1D), atomically confined plasmons at the edges of a zigzag MoS2 nanoribbon. The strongest plasmon originates from a metallic edge state localized on the sulfur dimers decorating the Mo edge of the ribbon. A detailed analysis of the dielectric function reveals that the observed deviations from the ideal 1D plasmon behavior result from single-particle transitions between the metallic edge state and the valence and conduction bands of the MoS2 sheet. The Mo and S edges of the ribbon are clearly distinguishable in calculated spatially resolved electron energy loss spectrum owing to the different plasmonic properties of the two edges. The edge plasmons could potentially be utilized for tuning the photocatalytic activity of MoS2 nanoparticles.
Original languageEnglish
JournalPhysical Review B
Volume90
Issue number16
Pages (from-to)161410
Number of pages5
ISSN0163-1829
DOIs
Publication statusPublished - 2014

Bibliographical note

©2014 American Physical Society

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