Abstract
The removal of NOx from the exhaust gases requires the oxidation of most abundant NO to NO2 or N2O5. The oxidation can be done by non-thermal plasma but the efficiency is limited due to the back-reaction of NO2 to NO by O radicals. Present contribution investigates the role of catalysts in the improvement of oxidation efficiency based on the stationary and time-dependent studies of the NOx oxidation at different reactor configurations and experimental conditions. The plasma produced active oxygen species (O, O3) were shown to play an important role in the reactions taking place on the catalyst surfaces while the exact mechanism and extent of the effect depended on the reactor configuration. The effect of catalyst at different experimental conditions was quantitatively described with the aid of analytical lumped kinetic models derived for the NOx oxidation when the catalyst was directly in contact with plasma or only with the ozone.
Original language | English |
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Title of host publication | Proceedings of the XXXIII International Conference on Phenomena in Ionized Gases (ICPIG 2017) |
Publisher | Instituto de Plasmas e Fusão Nuclear |
Publication date | 2017 |
Pages | 32 |
Publication status | Published - 2017 |
Event | 33rd International Conference on Phenomena in Ionized Gases (ICPIG 2017) - Estoril, Portugal Duration: 9 Jul 2017 → 14 Jul 2017 Conference number: 33 http://icpig2017.tecnico.ulisboa.pt/ |
Conference
Conference | 33rd International Conference on Phenomena in Ionized Gases (ICPIG 2017) |
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Number | 33 |
Country/Territory | Portugal |
City | Estoril |
Period | 09/07/2017 → 14/07/2017 |
Internet address |