Abstract
Herein, we describe a photoinduced multicomponent catalytic carboxylation protocol that streamlines the access to 13C-labeled carboxylic acids from simple olefin precursors, sulfinate salts and 13CO2. Site selectivity is dictated by the radical philicity of the starting precursors and reaction intermediates, resulting in either a four-component or a five-component endeavor.
Original language | English |
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Journal | ACS Catalysis |
Volume | 14 |
Issue number | 24 |
Pages (from-to) | 18633-18638 |
ISSN | 2155-5435 |
DOIs | |
Publication status | Published - 2024 |
Keywords
- Carbon dioxide
- Isotope labeling
- Multicomponent
- Olefins
- Site selectivity