Photocatalytic Multicomponent Carboxylation of Olefins and Sulfinate Salts with 13CO2

Julien R. Lyonnet, Álvaro Velasco-Rubio, Roman Abrams, Ha Phan, Kim Mühlfenzl, Xuemeng Chen, Alessandro Cerveri, José Tiago M. Correia, Márcio W. Paixão, Charles S. Elmore, Ruben Martin*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Herein, we describe a photoinduced multicomponent catalytic carboxylation protocol that streamlines the access to 13C-labeled carboxylic acids from simple olefin precursors, sulfinate salts and 13CO2. Site selectivity is dictated by the radical philicity of the starting precursors and reaction intermediates, resulting in either a four-component or a five-component endeavor.

Original languageEnglish
JournalACS Catalysis
Volume14
Issue number24
Pages (from-to)18633-18638
ISSN2155-5435
DOIs
Publication statusPublished - 2024

Keywords

  • Carbon dioxide
  • Isotope labeling
  • Multicomponent
  • Olefins
  • Site selectivity

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