Phase Equilibrium Measurements and Modeling of 1-Propanethiol+1-Butanethiol + CH4 in Methane Ternary System at 303, 336, and 368 K and Pressure Up to 9 MPa

Javeed A. Awan, Christophe Coquelet, Ioannis Tsivintzelis, Georgios Kontogeorgis

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Abstract

New vapor-liquid equilibrium (VLE) data for 1-propanethiol + 1-butanethiol + CH4 ternary system is reported. Measurements were performed at three different temperatures (303, 336, and 368 K), and the pressure ranged from 1 to 9 MPa. The total system pressure was maintained by CH4. The inlet mole fraction of 1-propanethiol (x = 5.43 x 10-1) and 1-butanethiol (x = 4.56 x 10-1) in the liquid phase were same in all experiments. A static analytic method was used for performing phase equilibrium measurements. The new VLE data have been modeled successfully with cubic-plus-association (CPA) equation of state.
Original languageEnglish
JournalJournal of Chemical and Engineering Data
Volume61
Issue number1
Pages (from-to)41-44
ISSN0021-9568
DOIs
Publication statusPublished - 2016

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