Performance and durability of solid oxide electrolysis cells

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Abstract

Solid oxide fuel cells produced at Riso National Laboratory have been tested as electrolysis cells by applying an external voltage. Results on initial performance and durability of such reversible solid oxide cells at temperatures from 750 to 950 degrees C and current densities from -0.25 A/cm(2) to -0.50 A/cm(2) are reported. The full cells have an initial area specific resistance as low as 0.27 Omega cm(2) for electrolysis operation at 850 degrees C. During galvanostatic long-term electrolysis tests, the cells were observed to passivate mainly during the first similar to 100 h of electrolysis. Cells that have been passivated during electrolysis tests can be partly activated again by operation in fuel cell mode or even at constant electrolysis conditions after several hundred hours of testing.
Original languageEnglish
JournalJournal of The Electrochemical Society
Volume153
Issue number9
Pages (from-to)A1741-A1747
ISSN0013-4651
DOIs
Publication statusPublished - 2006

Bibliographical note

Copyright The Electrochemical Society, Inc. [2006]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).

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