Partially fluorinated aarylene polyethers and their ternary blends with PBI and H3PO4.

Part II. Characterisation and fuel cell tests of the ternary membranes

Qingfeng Li, Jens Oluf Jensen, Chao Pan, Viktor Bandur, M. S. Nilsson, F. Schoenberger, A. Chromik, M. Hein, T. Haering, J Kerres, Niels Bjerrum

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Ternary blend membranes based on sulphonated partially fluorinated arylene polyether, polybenzimidazole (PBI) and phosphoric acid were prepared and characterised as electrolyte for high temperature proton exchange membrane fuel cells. Partially fluorinated arylene polyether was first prepared from polycondensation of decafluorobiphenyl with 2,2-bis(4-hydroxyphenyl)hexafluoropropane, followed by sulphonation with H2SO4/60% SO3, based on which binary blends with PBI were prepared and further doped with concentrated phosphoric acid at temperatures of up to 130 degrees C, Acid doping levels as high as 10-13 mol phosphoric acid per PBI repeat unit can be reached, showing small swelling and excellent mechanical strength. At an acid doping level of 11, a conductivity of 0.12 S cm(-1) was obtained at 175 degrees C and 10% relative humidity. Such a membrane exhibits a tensile strength of 6 MPa, elongation of 220% and modulus of 50 MPa at 150 degrees C. Based on these ternary membranes large MEAs with an active area of 256 cm(2) have been prepared for a 2 kW(el) stack showing good performance and reproducibility.
Original languageEnglish
JournalFuel Cells
Volume8
Issue number3-4
Pages (from-to)188-199
ISSN1615-6846
DOIs
Publication statusPublished - 2008

Cite this

Li, Qingfeng ; Jensen, Jens Oluf ; Pan, Chao ; Bandur, Viktor ; Nilsson, M. S. ; Schoenberger, F. ; Chromik, A. ; Hein, M. ; Haering, T. ; Kerres, J ; Bjerrum, Niels. / Partially fluorinated aarylene polyethers and their ternary blends with PBI and H3PO4. Part II. Characterisation and fuel cell tests of the ternary membranes. In: Fuel Cells. 2008 ; Vol. 8, No. 3-4. pp. 188-199.
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title = "Partially fluorinated aarylene polyethers and their ternary blends with PBI and H3PO4.: Part II. Characterisation and fuel cell tests of the ternary membranes",
abstract = "Ternary blend membranes based on sulphonated partially fluorinated arylene polyether, polybenzimidazole (PBI) and phosphoric acid were prepared and characterised as electrolyte for high temperature proton exchange membrane fuel cells. Partially fluorinated arylene polyether was first prepared from polycondensation of decafluorobiphenyl with 2,2-bis(4-hydroxyphenyl)hexafluoropropane, followed by sulphonation with H2SO4/60{\%} SO3, based on which binary blends with PBI were prepared and further doped with concentrated phosphoric acid at temperatures of up to 130 degrees C, Acid doping levels as high as 10-13 mol phosphoric acid per PBI repeat unit can be reached, showing small swelling and excellent mechanical strength. At an acid doping level of 11, a conductivity of 0.12 S cm(-1) was obtained at 175 degrees C and 10{\%} relative humidity. Such a membrane exhibits a tensile strength of 6 MPa, elongation of 220{\%} and modulus of 50 MPa at 150 degrees C. Based on these ternary membranes large MEAs with an active area of 256 cm(2) have been prepared for a 2 kW(el) stack showing good performance and reproducibility.",
author = "Qingfeng Li and Jensen, {Jens Oluf} and Chao Pan and Viktor Bandur and Nilsson, {M. S.} and F. Schoenberger and A. Chromik and M. Hein and T. Haering and J Kerres and Niels Bjerrum",
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Partially fluorinated aarylene polyethers and their ternary blends with PBI and H3PO4. Part II. Characterisation and fuel cell tests of the ternary membranes. / Li, Qingfeng; Jensen, Jens Oluf; Pan, Chao; Bandur, Viktor; Nilsson, M. S.; Schoenberger, F.; Chromik, A.; Hein, M.; Haering, T.; Kerres, J; Bjerrum, Niels.

In: Fuel Cells, Vol. 8, No. 3-4, 2008, p. 188-199.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Partially fluorinated aarylene polyethers and their ternary blends with PBI and H3PO4.

T2 - Part II. Characterisation and fuel cell tests of the ternary membranes

AU - Li, Qingfeng

AU - Jensen, Jens Oluf

AU - Pan, Chao

AU - Bandur, Viktor

AU - Nilsson, M. S.

AU - Schoenberger, F.

AU - Chromik, A.

AU - Hein, M.

AU - Haering, T.

AU - Kerres, J

AU - Bjerrum, Niels

PY - 2008

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N2 - Ternary blend membranes based on sulphonated partially fluorinated arylene polyether, polybenzimidazole (PBI) and phosphoric acid were prepared and characterised as electrolyte for high temperature proton exchange membrane fuel cells. Partially fluorinated arylene polyether was first prepared from polycondensation of decafluorobiphenyl with 2,2-bis(4-hydroxyphenyl)hexafluoropropane, followed by sulphonation with H2SO4/60% SO3, based on which binary blends with PBI were prepared and further doped with concentrated phosphoric acid at temperatures of up to 130 degrees C, Acid doping levels as high as 10-13 mol phosphoric acid per PBI repeat unit can be reached, showing small swelling and excellent mechanical strength. At an acid doping level of 11, a conductivity of 0.12 S cm(-1) was obtained at 175 degrees C and 10% relative humidity. Such a membrane exhibits a tensile strength of 6 MPa, elongation of 220% and modulus of 50 MPa at 150 degrees C. Based on these ternary membranes large MEAs with an active area of 256 cm(2) have been prepared for a 2 kW(el) stack showing good performance and reproducibility.

AB - Ternary blend membranes based on sulphonated partially fluorinated arylene polyether, polybenzimidazole (PBI) and phosphoric acid were prepared and characterised as electrolyte for high temperature proton exchange membrane fuel cells. Partially fluorinated arylene polyether was first prepared from polycondensation of decafluorobiphenyl with 2,2-bis(4-hydroxyphenyl)hexafluoropropane, followed by sulphonation with H2SO4/60% SO3, based on which binary blends with PBI were prepared and further doped with concentrated phosphoric acid at temperatures of up to 130 degrees C, Acid doping levels as high as 10-13 mol phosphoric acid per PBI repeat unit can be reached, showing small swelling and excellent mechanical strength. At an acid doping level of 11, a conductivity of 0.12 S cm(-1) was obtained at 175 degrees C and 10% relative humidity. Such a membrane exhibits a tensile strength of 6 MPa, elongation of 220% and modulus of 50 MPa at 150 degrees C. Based on these ternary membranes large MEAs with an active area of 256 cm(2) have been prepared for a 2 kW(el) stack showing good performance and reproducibility.

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