Organic Metals. Systematic Molecular Modifications of Hexamethylenetetraheterofulvalene Donors

E. M. Engler, V. V. Patel, Jan Rud Andersen, R. R. Schumaker, A. A. Fukushima

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    Two synthetic approaches for modifying hexamethylenetetraheterofulvalene donors are described for the purpose of perturbing in a systematic way the interesting solid state properties of the TCNQ salts of the parent systems. The first approach consists of a steric modification in which a methyl group is introduced into the outer five-membered rings of the parent molecules. The second type of modification involves an electronic perturbation in which the outer five-membered alkyl rings are replaced with fused thiophene derivatives
    Original languageEnglish
    JournalJournal of the American Chemical Society
    Volume100
    Issue number12
    Pages (from-to)3769-3776
    ISSN0002-7863
    DOIs
    Publication statusPublished - 1978

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