Organic Metals. Systematic Molecular Modifications of Hexamethylenetetraheterofulvalene Donors

E. M. Engler; V. V. Patel; Jan Rud Andersen; R. R. Schumaker; A. A. Fukushima

doi:10.1021/ja00480a019

Organic Metals. Systematic Molecular Modifications of Hexamethylenetetraheterofulvalene Donors

E. M. Engler, V. V. Patel, Jan Rud Andersen, R. R. Schumaker, A. A. Fukushima

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Two synthetic approaches for modifying hexamethylenetetraheterofulvalene donors are described for the purpose of perturbing in a systematic way the interesting solid state properties of the TCNQ salts of the parent systems. The first approach consists of a steric modification in which a methyl group is introduced into the outer five-membered rings of the parent molecules. The second type of modification involves an electronic perturbation in which the outer five-membered alkyl rings are replaced with fused thiophene derivatives

Original language	English
Journal	Journal of the American Chemical Society
Volume	100
Issue number	12
Pages (from-to)	3769-3776
ISSN	0002-7863
DOIs	https://doi.org/10.1021/ja00480a019
Publication status	Published - 1978

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title = "Organic Metals. Systematic Molecular Modifications of Hexamethylenetetraheterofulvalene Donors",

abstract = "Two synthetic approaches for modifying hexamethylenetetraheterofulvalene donors are described for the purpose of perturbing in a systematic way the interesting solid state properties of the TCNQ salts of the parent systems. The first approach consists of a steric modification in which a methyl group is introduced into the outer five-membered rings of the parent molecules. The second type of modification involves an electronic perturbation in which the outer five-membered alkyl rings are replaced with fused thiophene derivatives",

author = "Engler, {E. M.} and Patel, {V. V.} and Andersen, {Jan Rud} and Schumaker, {R. R.} and Fukushima, {A. A.}",

year = "1978",

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language = "English",

volume = "100",

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journal = "Journal of the American Chemical Society",

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T1 - Organic Metals. Systematic Molecular Modifications of Hexamethylenetetraheterofulvalene Donors

AU - Engler, E. M.

AU - Patel, V. V.

AU - Andersen, Jan Rud

AU - Schumaker, R. R.

AU - Fukushima, A. A.

PY - 1978

Y1 - 1978

N2 - Two synthetic approaches for modifying hexamethylenetetraheterofulvalene donors are described for the purpose of perturbing in a systematic way the interesting solid state properties of the TCNQ salts of the parent systems. The first approach consists of a steric modification in which a methyl group is introduced into the outer five-membered rings of the parent molecules. The second type of modification involves an electronic perturbation in which the outer five-membered alkyl rings are replaced with fused thiophene derivatives

AB - Two synthetic approaches for modifying hexamethylenetetraheterofulvalene donors are described for the purpose of perturbing in a systematic way the interesting solid state properties of the TCNQ salts of the parent systems. The first approach consists of a steric modification in which a methyl group is introduced into the outer five-membered rings of the parent molecules. The second type of modification involves an electronic perturbation in which the outer five-membered alkyl rings are replaced with fused thiophene derivatives

U2 - 10.1021/ja00480a019

DO - 10.1021/ja00480a019

M3 - Journal article

SN - 0002-7863

VL - 100

SP - 3769

EP - 3776

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 12

ER -

Organic Metals. Systematic Molecular Modifications of Hexamethylenetetraheterofulvalene Donors

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