Optimization and Durability of Reversible Solid Oxide Cells

X. Sun*, B. R. Sudireddy, X. Tong, M. Chen, K. Brodersen, A. Hauch

*Corresponding author for this work

Research output: Contribution to journalConference articleResearchpeer-review

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Abstract

Reversible solid oxide cells (rSOCs) hold a considerable potential to play a very important role in the future energy system. The present work focuses on understanding the influence of initial cell performance, duration of the operation when cycling between SOFC and SOEC modes, current density and temperature on the durability of rSOCs. Two different cell designs are developed and their performance in reversible operation was evaluated. Type I is Ni-yttria stabilized zirconia (Ni-YSZ) fuel electrode supported planar SOCs, with a LSC-CGO (La0.6Sr0.4CoO3-δ-Ce0.9Gd0.1O2-δ) composite oxygen electrode, Type II is the same fuel-electrode supported half-cell with CGO oxygen electrode backbone infiltrated with LSC nano-electrocatalysts. Comparable degradation rates of below 5-10%/1000 hours were achieved for Type I cells operated at ±0.5 A/cm2, or for Type II cells operated at ±1.25 A/cm2. The electrochemical performance and durability of both cell types are compared and the observed degradation behavior is discussed.
Original languageEnglish
JournalECS Transactions
Volume91
Issue number1
Pages (from-to)2631-2639
ISSN1938-5862
DOIs
Publication statusPublished - 2019
Event16th International Symposium on Solid Oxide Fuel Cells - Kyoto, Japan
Duration: 8 Sep 201913 Sep 2019
Conference number: 16
http://www.eguchi-lab.ehcc.kyoto-u.ac.jp/SOFC_XVI/#

Conference

Conference16th International Symposium on Solid Oxide Fuel Cells
Number16
CountryJapan
CityKyoto
Period08/09/201913/09/2019
Internet address

Cite this

@inproceedings{e15707dd961749438d273b603b016c19,
title = "Optimization and Durability of Reversible Solid Oxide Cells",
abstract = "Reversible solid oxide cells (rSOCs) hold a considerable potential to play a very important role in the future energy system. The present work focuses on understanding the influence of initial cell performance, duration of the operation when cycling between SOFC and SOEC modes, current density and temperature on the durability of rSOCs. Two different cell designs are developed and their performance in reversible operation was evaluated. Type I is Ni-yttria stabilized zirconia (Ni-YSZ) fuel electrode supported planar SOCs, with a LSC-CGO (La0.6Sr0.4CoO3-δ-Ce0.9Gd0.1O2-δ) composite oxygen electrode, Type II is the same fuel-electrode supported half-cell with CGO oxygen electrode backbone infiltrated with LSC nano-electrocatalysts. Comparable degradation rates of below 5-10{\%}/1000 hours were achieved for Type I cells operated at ±0.5 A/cm2, or for Type II cells operated at ±1.25 A/cm2. The electrochemical performance and durability of both cell types are compared and the observed degradation behavior is discussed.",
author = "X. Sun and Sudireddy, {B. R.} and X. Tong and M. Chen and K. Brodersen and A. Hauch",
year = "2019",
doi = "10.1149/09101.2631ecst",
language = "English",
volume = "91",
pages = "2631--2639",
journal = "E C S Transactions",
issn = "1938-5862",
publisher = "The Electrochemical Society",
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}

Optimization and Durability of Reversible Solid Oxide Cells. / Sun, X.; Sudireddy, B. R.; Tong, X.; Chen, M.; Brodersen, K.; Hauch, A.

In: ECS Transactions, Vol. 91, No. 1, 2019, p. 2631-2639.

Research output: Contribution to journalConference articleResearchpeer-review

TY - GEN

T1 - Optimization and Durability of Reversible Solid Oxide Cells

AU - Sun, X.

AU - Sudireddy, B. R.

AU - Tong, X.

AU - Chen, M.

AU - Brodersen, K.

AU - Hauch, A.

PY - 2019

Y1 - 2019

N2 - Reversible solid oxide cells (rSOCs) hold a considerable potential to play a very important role in the future energy system. The present work focuses on understanding the influence of initial cell performance, duration of the operation when cycling between SOFC and SOEC modes, current density and temperature on the durability of rSOCs. Two different cell designs are developed and their performance in reversible operation was evaluated. Type I is Ni-yttria stabilized zirconia (Ni-YSZ) fuel electrode supported planar SOCs, with a LSC-CGO (La0.6Sr0.4CoO3-δ-Ce0.9Gd0.1O2-δ) composite oxygen electrode, Type II is the same fuel-electrode supported half-cell with CGO oxygen electrode backbone infiltrated with LSC nano-electrocatalysts. Comparable degradation rates of below 5-10%/1000 hours were achieved for Type I cells operated at ±0.5 A/cm2, or for Type II cells operated at ±1.25 A/cm2. The electrochemical performance and durability of both cell types are compared and the observed degradation behavior is discussed.

AB - Reversible solid oxide cells (rSOCs) hold a considerable potential to play a very important role in the future energy system. The present work focuses on understanding the influence of initial cell performance, duration of the operation when cycling between SOFC and SOEC modes, current density and temperature on the durability of rSOCs. Two different cell designs are developed and their performance in reversible operation was evaluated. Type I is Ni-yttria stabilized zirconia (Ni-YSZ) fuel electrode supported planar SOCs, with a LSC-CGO (La0.6Sr0.4CoO3-δ-Ce0.9Gd0.1O2-δ) composite oxygen electrode, Type II is the same fuel-electrode supported half-cell with CGO oxygen electrode backbone infiltrated with LSC nano-electrocatalysts. Comparable degradation rates of below 5-10%/1000 hours were achieved for Type I cells operated at ±0.5 A/cm2, or for Type II cells operated at ±1.25 A/cm2. The electrochemical performance and durability of both cell types are compared and the observed degradation behavior is discussed.

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