Abstract
Alpha-Chloro sulfenyl chlorides such as 1 and 4 could not be
reduced to the corresponding disulfides. Under reducing conditions
they are instead dechlorinated to the corresponding thiocarbonyl
compounds. Starting from the chroman-4-one derivatives 1 a number
of 1,3,4-oxadithiins 3 have been prepared. Sulfenyl chlorides 1
and 4 have been derivatized with p-toluenesulfinate, methoxide,
and cyanide ions as well as with primary and secondary amines,
with thiophenol and with thiobenzoic acid. The molecular structure
of thiocyanate 8a has been determined by X-ray crystallography.
| Original language | English |
|---|---|
| Journal | Sulfur Letters |
| Volume | 22(1) |
| Pages (from-to) | 19-32 |
| Publication status | Published - 1998 |