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Nitridation Resistance of High-temperature Resistant Cast Alloys - The Effect of Alumina Scales on High-temperature Ammonia Nitridation

  • Benjamin Aymans
  • , Pedro Imizcoz
  • , Pablo Cardin
  • , Dietlinde Jakobi
  • , Matteo Villa
  • , Marcel A.J. Somers
  • Schmidt + Clemens GmbH + Co. KG

Research output: Chapter in Book/Report/Conference proceeding › Article in proceedings › Research › peer-review

Abstract

Energy vectors, like ammonia as a “hydrogen carrier”, appears to be the ideal solution to reduce greenhouse gas emissions in the energy sector. The carrier vector ammonia has to be cracked into its elements N and H in an endothermic process named Ammonia Cracking, which shares similarities with the steam reforming process. Therefore, the application of centrifugally cast tubes of austenitic high temperature resistant Cr-Ni-Fe alloys is highly probable for ammonia cracking plants due to their high corrosion and excellent creep resistance. This study focuses on the suitability of centrifugally cast austenitic Cr-Ni-Fe-Al alloys forming protective Al2O3 scales under nitridation in ammonia. The influence of alumina scale properties is also addressed. Metallurgical investigations focus on revealing the degradation mechanisms in gas atmospheres of high nitrogen activity.

Original languageEnglish
Title of host publicationAmmonia Plant Safety and Related Facilities
PublisherAmerican Institute of Chemical Engineers
Publication date2025
Pages131-143
Publication statusPublished - 2025
Event69th Annual Safety in Ammonia Plants and Related Facilities Symposium 2025 - Atlanta, United States
Duration: 7 Sept 2025 → 11 Sept 2025

Conference

Conference69th Annual Safety in Ammonia Plants and Related Facilities Symposium 2025
Country/TerritoryUnited States
CityAtlanta
Period07/09/2025 → 11/09/2025
SeriesAmmonia Plant Safety and Related Facilities
ISSN0360-7011

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