Abstract
The microscopic Grüneisen parameters in RbBr have been determined for 44 acoustic modes in the main symmetry directions Δ, Σ, and Λ by inelastic neutron scattering under hydrostatic pressure. The experimental data are well described within the framework of a breathing-shell model, which includes third-order anharmonic contributions. The thermal-expansion coefficient has been calculated in the temperature range 0-300 K. The results are in good agreement with the experimental data.
Original language | English |
---|---|
Journal | Physical Review B |
Volume | 29 |
Issue number | 10 |
Pages (from-to) | 5805-5813 |
ISSN | 2469-9950 |
DOIs | |
Publication status | Published - 1984 |