Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry

Xenia Trier; Jan H. Christensen; Wilfried M. A. Niessen

Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry

Xenia Trier, Jan H. Christensen, Wilfried M. A. Niessen

National Food Institute

Research output: Contribution to conference › Poster › Research › peer-review

483 Downloads (Pure)

Abstract

Fluorotelomer alcohols (FTOHs) are used to synthesize fluorinated surfactants, which form bioaccumulative perfluorinated degradation products, which are toxic to humans and the environment. To facilitate screening for FTOH-derived surfactants by LC-ESI–-MS, we identified product ions of FTOHs, and propose FTOH fragmentation pathways on two MS instruments. By extraction of FTOH basepeak ions from accurate mass spectra, homologues series of peaks showed up in an industrial blend of FTOH-derived fluoroacrylates used in food paper packaging.

Original language	English
Publication date	2013
Number of pages	1
Publication status	Published - 2013
Event	39th International Symposium on High-Performance-Liquid-Phase Separations and Related Techniques (HPLC2013) - Amsterdam, Netherlands Duration: 16 Jun 2013 → 20 Jun 2013 http://www.hplc2013.org/

Conference

Conference	39th International Symposium on High-Performance-Liquid-Phase Separations and Related Techniques (HPLC2013)
Country/Territory	Netherlands
City	Amsterdam
Period	16/06/2013 → 20/06/2013
Internet address	http://www.hplc2013.org/

Access to Document

Prod11372700419448Final published version, 727 KB

OpenUrl availability

Full text

Cite this

Trier, X., Christensen, J. H., & Niessen, W. M. A. (2013). Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry. Poster session presented at 39th International Symposium on High-Performance-Liquid-Phase Separations and Related Techniques (HPLC2013), Amsterdam, Netherlands.

Trier, Xenia ; Christensen, Jan H. ; Niessen, Wilfried M. A. / Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry. Poster session presented at 39th International Symposium on High-Performance-Liquid-Phase Separations and Related Techniques (HPLC2013), Amsterdam, Netherlands.1 p.

@conference{62b4c8ea96f6415a8bd1245922d1d546,

title = "Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry",

abstract = "Fluorotelomer alcohols (FTOHs) are used to synthesize fluorinated surfactants, which form bioaccumulative perfluorinated degradation products, which are toxic to humans and the environment. To facilitate screening for FTOH-derived surfactants by LC-ESI–-MS, we identified product ions of FTOHs, and propose FTOH fragmentation pathways on two MS instruments. By extraction of FTOH basepeak ions from accurate mass spectra, homologues series of peaks showed up in an industrial blend of FTOH-derived fluoroacrylates used in food paper packaging.",

author = "Xenia Trier and Christensen, {Jan H.} and Niessen, {Wilfried M. A.}",

year = "2013",

language = "English",

note = "39th International Symposium on High-Performance-Liquid-Phase Separations and Related Techniques (HPLC2013) ; Conference date: 16-06-2013 Through 20-06-2013",

url = "http://www.hplc2013.org/",

}

Trier, X, Christensen, JH & Niessen, WMA 2013, 'Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry', 39th International Symposium on High-Performance-Liquid-Phase Separations and Related Techniques (HPLC2013), Amsterdam, Netherlands, 16/06/2013 - 20/06/2013.

Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry. / Trier, Xenia; Christensen, Jan H.; Niessen, Wilfried M. A.
2013. Poster session presented at 39th International Symposium on High-Performance-Liquid-Phase Separations and Related Techniques (HPLC2013), Amsterdam, Netherlands.

Research output: Contribution to conference › Poster › Research › peer-review

TY - CONF

T1 - Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry

AU - Trier, Xenia

AU - Christensen, Jan H.

AU - Niessen, Wilfried M. A.

PY - 2013

Y1 - 2013

N2 - Fluorotelomer alcohols (FTOHs) are used to synthesize fluorinated surfactants, which form bioaccumulative perfluorinated degradation products, which are toxic to humans and the environment. To facilitate screening for FTOH-derived surfactants by LC-ESI–-MS, we identified product ions of FTOHs, and propose FTOH fragmentation pathways on two MS instruments. By extraction of FTOH basepeak ions from accurate mass spectra, homologues series of peaks showed up in an industrial blend of FTOH-derived fluoroacrylates used in food paper packaging.

AB - Fluorotelomer alcohols (FTOHs) are used to synthesize fluorinated surfactants, which form bioaccumulative perfluorinated degradation products, which are toxic to humans and the environment. To facilitate screening for FTOH-derived surfactants by LC-ESI–-MS, we identified product ions of FTOHs, and propose FTOH fragmentation pathways on two MS instruments. By extraction of FTOH basepeak ions from accurate mass spectra, homologues series of peaks showed up in an industrial blend of FTOH-derived fluoroacrylates used in food paper packaging.

M3 - Poster

T2 - 39th International Symposium on High-Performance-Liquid-Phase Separations and Related Techniques (HPLC2013)

Y2 - 16 June 2013 through 20 June 2013

ER -

Trier X, Christensen JH, Niessen WMA. Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry. 2013. Poster session presented at 39th International Symposium on High-Performance-Liquid-Phase Separations and Related Techniques (HPLC2013), Amsterdam, Netherlands.

Negative electrospray ionisation of fluorotelomer alcohols (FTOH) and FTOH-derived acrylate surfactants by liquid chromatography coupled to accurate (tandem) mass spectrometry

Abstract

Conference

Access to Document

OpenUrl availability

Fingerprint

Cite this