Near interface ionic transport in oxygen vacancy stabilized cubic zirconium oxide thin films

Mohsin Raza; Simone Sanna; Lucia Dos Santos Gómez; Eric Gautron; Abdel Aziz El Mel; Nini Pryds; Rony Snyders; Stéphanos Konstantinidis; Vincenzo Esposito

doi:10.1039/c8cp05465g

Near interface ionic transport in oxygen vacancy stabilized cubic zirconium oxide thin films

Mohsin Raza, Simone Sanna, Lucia Dos Santos Gómez, Eric Gautron, Abdel Aziz El Mel, Nini Pryds, Rony Snyders, Stéphanos Konstantinidis, Vincenzo Esposito^*

^*Corresponding author for this work

Department of Energy Conversion and Storage

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The cubic phase of pure zirconia (ZrO2) is stabilized in dense thin films through a controlled introduction of oxygen vacancies (O defects) by cold-plasma-based sputtering deposition. Here, we show that the cubic crystals present at the film/substrate interface near-region exhibit fast ionic transport, which is superior to what is obtained with similar yttrium-stabilized cubic zirconia thin films.

Original language	English
Journal	Physical Chemistry Chemical Physics
Volume	20
Issue number	41
Pages (from-to)	26068-26071
ISSN	1463-9076
DOIs	https://doi.org/10.1039/c8cp05465g
Publication status	Published - 2018

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title = "Near interface ionic transport in oxygen vacancy stabilized cubic zirconium oxide thin films",

abstract = "The cubic phase of pure zirconia (ZrO2) is stabilized in dense thin films through a controlled introduction of oxygen vacancies (O defects) by cold-plasma-based sputtering deposition. Here, we show that the cubic crystals present at the film/substrate interface near-region exhibit fast ionic transport, which is superior to what is obtained with similar yttrium-stabilized cubic zirconia thin films.",

author = "Mohsin Raza and Simone Sanna and {Dos Santos G{\'o}mez}, Lucia and Eric Gautron and {El Mel}, {Abdel Aziz} and Nini Pryds and Rony Snyders and St{\'e}phanos Konstantinidis and Vincenzo Esposito",

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language = "English",

volume = "20",

pages = "26068--26071",

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publisher = "Royal Society of Chemistry",

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T1 - Near interface ionic transport in oxygen vacancy stabilized cubic zirconium oxide thin films

AU - Raza, Mohsin

AU - Sanna, Simone

AU - Dos Santos Gómez, Lucia

AU - Gautron, Eric

AU - El Mel, Abdel Aziz

AU - Pryds, Nini

AU - Snyders, Rony

AU - Konstantinidis, Stéphanos

AU - Esposito, Vincenzo

PY - 2018

Y1 - 2018

N2 - The cubic phase of pure zirconia (ZrO2) is stabilized in dense thin films through a controlled introduction of oxygen vacancies (O defects) by cold-plasma-based sputtering deposition. Here, we show that the cubic crystals present at the film/substrate interface near-region exhibit fast ionic transport, which is superior to what is obtained with similar yttrium-stabilized cubic zirconia thin films.

AB - The cubic phase of pure zirconia (ZrO2) is stabilized in dense thin films through a controlled introduction of oxygen vacancies (O defects) by cold-plasma-based sputtering deposition. Here, we show that the cubic crystals present at the film/substrate interface near-region exhibit fast ionic transport, which is superior to what is obtained with similar yttrium-stabilized cubic zirconia thin films.

U2 - 10.1039/c8cp05465g

DO - 10.1039/c8cp05465g

M3 - Journal article

C2 - 30307015

SN - 1463-9076

VL - 20

SP - 26068

EP - 26071

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 41

ER -

Near interface ionic transport in oxygen vacancy stabilized cubic zirconium oxide thin films

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