Nanostructured PLD-grown gadolinia doped ceria: Chemical and structural characterization by transmission electron microscopy techniques

Katarzyna Agnieszka Rodrigo, Hsiang-Jen Wang, Sebastian Heiroth, Nini Pryds, Luise Theil Kuhn, Vincenzo Esposito, Søren Linderoth, Jørgen Schou, T. Lippert

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    The morphology as well as the spatially resolved elemental and chemical characterization of 10 mol% gadolinia doped ceria (CGO10) structures prepared by pulsed laser deposition (PLD) technique are investigated by scanning transmission electron microscopy accompanied with electron energy loss spectroscopy and energy dispersive X-ray spectroscopy. A dense, columnar and structurally inhomogeneous CGO10 film, i.e. exhibiting grain size refinement across the film thickness, is obtained in the deposition process. The cerium M4,5 edges, used to monitor the local electronic structure of the grains, indicate apparent variation of the ceria valence state across and along the film. No element segregation to the grain boundaries is detected. These results are discussed in the context of solid oxide fuel cell applications.
    Original languageEnglish
    JournalApplied Surface Science
    Volume257
    Issue number12
    Pages (from-to)5341-5346
    ISSN0169-4332
    DOIs
    Publication statusPublished - 2011

    Keywords

    • Solid Oxide Fuel Cells
    • Fuel Cells and Hydrogen

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