Nanomorphology of graphene and CNT reinforced polymer and its effect on damage: Micromechanical numerical study

Alessandro Pontefisso, Leon Mishnaevsky

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

The effect of morphology, shapes and distribution of nanoscale carbon reinforcement in polymers on their strength and damage resistance is studied using computational micromechanical modeling. A new software and approach were developed for the automatic generation of finite element unit cell models of nanocomposites with inclusions of arbitrary and complex shapes. The effect of curved, zigzagged, snakelike shapes of real carbon nanotubes, as well as re-stacking of graphene on the damage evolution was studied in the computational experiments based on the developed code. The potential of hybrid (carbon nanotubes and graphene) nanoscale reinforcement was studied with view on its effect of damage resistance. It was demonstrated that idealized, cylinder like models of carbon nanotubes in polymers lead to an underestimation of the stress concentration and damage likelihood in the nanocomposites. The main damage mechanisms in CNT reinforced polymers are debonding and pull-out/fiber bridging, while in graphene reinforced polymers the main role is played by crack deviation and stack splitting, with following micro-crack merging. The potential of hybrid (carbon nanotubes and graphene) nanoscale reinforcement was studied with view on its effect of damage resistance. (C) 2016 Elsevier Ltd. All rights reserved.
Original languageEnglish
JournalComposites Part B: Engineering
Volume96
Pages (from-to)338-349
ISSN1359-8368
DOIs
Publication statusPublished - 2016

Keywords

  • ENGINEERING,
  • MATERIALS
  • MECHANICAL-PROPERTIES
  • CARBON NANOTUBES
  • EPOXY COMPOSITES
  • FRACTURE-TOUGHNESS
  • TOUGHENING MECHANISMS
  • THERMAL-PROPERTIES
  • NANOCOMPOSITES
  • FATIGUE
  • OXIDE
  • MULTISCALE
  • Polymer-matrix composites (PMCs)
  • Fracture toughness
  • Finite element analysis (FEA)
  • Nanocomposite
  • Ceramics and Composites
  • Mechanics of Materials
  • Industrial and Manufacturing Engineering
  • Mechanical Engineering
  • A. Polymer-matrix composites (PMCs)
  • B. Fracture toughness
  • C. Finite element analysis (FEA)
  • D. Nanocomposite
  • Carbon nanotubes
  • Cracks
  • Finite element method
  • Graphene
  • Nanocomposites
  • Nanotechnology
  • Nanotubes
  • Reinforced plastics
  • Reinforcement
  • Yarn
  • Automatic Generation
  • Computational experiment
  • Damage resistance
  • Micro-mechanical modeling
  • Nanoscale reinforcements
  • Polymer Matrix Composites (PMCs)
  • Reinforced polymers
  • Unit cell models
  • Polymer matrix composites

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