Nanocomposite YSZ-NiO Particles with Tailored Structure Synthesized in a Two-Stage Continuous Hydrothermal Flow Reactor

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Abstract

The increasing amount of fluctuating electricity generation from renewable sources requires a flexible energy system and storage technologies to ensure that energy services can be covered in a stable and affordable manner. In order to become truly independent from fossil fuels, increasing the performance of energy storage and conversion devices such as fuel cells, electrolyzers and batteries is important. One promising approach to further improve these devices is the use of carefully structured nanosized materials. Nano-composite particles combining different materials in advanced geometries like core-shell structures or surface decorated particles could exhibit better performance compared with single phase materials. To obtain such advanced structures is the aim of the ProEco project (www.proeco.dk). In this project, a two-stage continuous reactor is built and used to synthesize such nano-composites.

Here we report on the design of the two-stage continuous hydrothermal flow synthesis reactor and first results on obtaining structured nano-composite consisting of yttria-stabilized zirconia (YSZ) and NiO materials. These materials are commonly applied in the fuel electrodes of today’s state-of-the-art solid oxide fuel and electrolysis cells. The prepared particles were characterized by X-ray powder diffraction, (high resolution) transmission electron microscopy, scanning tunnel transmission microscopy and Raman spectroscopy in order to determine crystal structure, particle size, surface morphology and element distribution.
Original languageEnglish
Article number2953
JournalElectrochemical Society. Meeting Abstracts (Online)
VolumeMA2016-02
ISSN2151-2043
Publication statusPublished - 2016
EventPRiME 2016/230th ECS Meeting - Honolulu, United States
Duration: 2 Oct 20167 Oct 2016
http://prime-intl.org/

Conference

ConferencePRiME 2016/230th ECS Meeting
CountryUnited States
CityHonolulu
Period02/10/201607/10/2016
Internet address

Cite this

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title = "Nanocomposite YSZ-NiO Particles with Tailored Structure Synthesized in a Two-Stage Continuous Hydrothermal Flow Reactor",
abstract = "The increasing amount of fluctuating electricity generation from renewable sources requires a flexible energy system and storage technologies to ensure that energy services can be covered in a stable and affordable manner. In order to become truly independent from fossil fuels, increasing the performance of energy storage and conversion devices such as fuel cells, electrolyzers and batteries is important. One promising approach to further improve these devices is the use of carefully structured nanosized materials. Nano-composite particles combining different materials in advanced geometries like core-shell structures or surface decorated particles could exhibit better performance compared with single phase materials. To obtain such advanced structures is the aim of the ProEco project (www.proeco.dk). In this project, a two-stage continuous reactor is built and used to synthesize such nano-composites. Here we report on the design of the two-stage continuous hydrothermal flow synthesis reactor and first results on obtaining structured nano-composite consisting of yttria-stabilized zirconia (YSZ) and NiO materials. These materials are commonly applied in the fuel electrodes of today’s state-of-the-art solid oxide fuel and electrolysis cells. The prepared particles were characterized by X-ray powder diffraction, (high resolution) transmission electron microscopy, scanning tunnel transmission microscopy and Raman spectroscopy in order to determine crystal structure, particle size, surface morphology and element distribution.",
author = "Philipp Zielke and Yu Xu and Wolff-Ragnar Kiebach and Simonsen, {S{\o}ren Bredmose} and Poul Norby and Hendriksen, {Peter Vang}",
year = "2016",
language = "English",
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journal = "Electrochemical Society. Meeting Abstracts (Online)",
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TY - ABST

T1 - Nanocomposite YSZ-NiO Particles with Tailored Structure Synthesized in a Two-Stage Continuous Hydrothermal Flow Reactor

AU - Zielke, Philipp

AU - Xu, Yu

AU - Kiebach, Wolff-Ragnar

AU - Simonsen, Søren Bredmose

AU - Norby, Poul

AU - Hendriksen, Peter Vang

PY - 2016

Y1 - 2016

N2 - The increasing amount of fluctuating electricity generation from renewable sources requires a flexible energy system and storage technologies to ensure that energy services can be covered in a stable and affordable manner. In order to become truly independent from fossil fuels, increasing the performance of energy storage and conversion devices such as fuel cells, electrolyzers and batteries is important. One promising approach to further improve these devices is the use of carefully structured nanosized materials. Nano-composite particles combining different materials in advanced geometries like core-shell structures or surface decorated particles could exhibit better performance compared with single phase materials. To obtain such advanced structures is the aim of the ProEco project (www.proeco.dk). In this project, a two-stage continuous reactor is built and used to synthesize such nano-composites. Here we report on the design of the two-stage continuous hydrothermal flow synthesis reactor and first results on obtaining structured nano-composite consisting of yttria-stabilized zirconia (YSZ) and NiO materials. These materials are commonly applied in the fuel electrodes of today’s state-of-the-art solid oxide fuel and electrolysis cells. The prepared particles were characterized by X-ray powder diffraction, (high resolution) transmission electron microscopy, scanning tunnel transmission microscopy and Raman spectroscopy in order to determine crystal structure, particle size, surface morphology and element distribution.

AB - The increasing amount of fluctuating electricity generation from renewable sources requires a flexible energy system and storage technologies to ensure that energy services can be covered in a stable and affordable manner. In order to become truly independent from fossil fuels, increasing the performance of energy storage and conversion devices such as fuel cells, electrolyzers and batteries is important. One promising approach to further improve these devices is the use of carefully structured nanosized materials. Nano-composite particles combining different materials in advanced geometries like core-shell structures or surface decorated particles could exhibit better performance compared with single phase materials. To obtain such advanced structures is the aim of the ProEco project (www.proeco.dk). In this project, a two-stage continuous reactor is built and used to synthesize such nano-composites. Here we report on the design of the two-stage continuous hydrothermal flow synthesis reactor and first results on obtaining structured nano-composite consisting of yttria-stabilized zirconia (YSZ) and NiO materials. These materials are commonly applied in the fuel electrodes of today’s state-of-the-art solid oxide fuel and electrolysis cells. The prepared particles were characterized by X-ray powder diffraction, (high resolution) transmission electron microscopy, scanning tunnel transmission microscopy and Raman spectroscopy in order to determine crystal structure, particle size, surface morphology and element distribution.

M3 - Conference abstract in journal

VL - MA2016-02

JO - Electrochemical Society. Meeting Abstracts (Online)

JF - Electrochemical Society. Meeting Abstracts (Online)

SN - 2151-2043

M1 - 2953

ER -