Abstract
Fused-pentagons results in an increase of local steric strain according to the isolated pentagon rule (IPR), and for all reported non-IPR clusterfullerenes multiple (two or three) metals are required to stabilize the strained fused-pentagons, making it difficult to access the single-atom properties. Herein, we report the syntheses and isolations of novel non-IPR mononuclear clusterfullerenes MNC@C76 (M=Tb, Y), in which one pair of strained fused-pentagon is stabilized by a mononuclear cluster. The molecular structures of MNC@C76 (M=Tb, Y) were determined unambiguously by single-crystal
X-ray diffraction, featuring a non-IPR C2v(19138)-C76 cage entrapping a nearly linear MNC cluster, which is remarkably different from the triangular MNC cluster within the reported analogous clusterfullerenes based on IPR-obeying C82 cages. The TbNC@C76 molecule is found to be a field-induced singlemolecule magnet (SMM).
X-ray diffraction, featuring a non-IPR C2v(19138)-C76 cage entrapping a nearly linear MNC cluster, which is remarkably different from the triangular MNC cluster within the reported analogous clusterfullerenes based on IPR-obeying C82 cages. The TbNC@C76 molecule is found to be a field-induced singlemolecule magnet (SMM).
Original language | English |
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Journal | Angewandte Chemie International Edition |
Volume | 129 |
Issue number | 7 |
Pages (from-to) | 1856-1860 |
ISSN | 1433-7851 |
DOIs | |
Publication status | Published - 2017 |