Modeling Electrolyte Solutions with the extended universal quasichemical (UNIQUAC) Model

Kaj Thomsen

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

The extended universal quasichemical (UNIQUAC) model is a thermodynamic model for solutions containing electrolytes and non-electrolytes. The model is a gibbs excess function consisting of a Debye-Hückel term and a standard UNIQUAC term. The model only requires binary, ion specific interaction parameters. A unique choice of standard states makes the model able to reproduce solid-liquid, vapor-liquid, and liquid-liquid phase equilibria as well as thermal properties of electrolyte solutions using one set of parameters.
Original languageEnglish
JournalJournal of Pure and Applied Chemistry
Volume77
Issue number3
Pages (from-to)531-542
ISSN0033-4545
Publication statusPublished - 2005

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