Mixed phase Pt-Ru catalyst for direct methanol fuel cell anode by flame aerosol synthesis

Debasish Chakraborty, H. Bischoff, Ib Chorkendorff, Tue Johannessen

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A spray-flame aerosol catalyzation technique was studied for producing Pt-Ru anode electrodes for the direct methanol fuel cell. Catalysts were produced as aerosol nanoparticles in a spray-flame reactor and deposited directly as a thin layer on the gas diffusion layer. The as-prepared catalyst was found to be a mixture of nanocrystalline, mostly unalloyed Pt and an amorphous phase mostly of Ru and to a lesser extent of Pt oxides on top of the crystalline phase. The flame-produced Pt1Ru1 demonstrated similar onset potential but similar to 60% higher activity compared to commercially available Pt1Ru1/Vulcan carbon. The kinetics of methanol oxidation on the mixed phase catalyst was also explored by electrochemical impedance spectroscopy. (c) 2005 The Electrochemical Society.
Original languageEnglish
JournalJournal of The Electrochemical Society
Issue number12
Pages (from-to)A2357-A2363
Publication statusPublished - 2005

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Copyright The Electrochemical Society, Inc. [2005]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).

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