Microstructure and thermoelectric properties of screen-printed thick-films of misfit-layered cobalt oxides with Ag addition

Ngo Van Nong, Alfred Junio Samson, Nini Pryds, Søren Linderoth

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    Abstract

    Thermoelectric properties of thick (~60 μm) films prepared by a screen-printing technique using p-type misfit-layered cobalt oxide Ca3Co4O9+δ with Ag addition have been studied. The screen-printed films were sintered in air at various temperatures ranging from 973 K to 1223 K. After each sintering process, crystal and microstructure analyses were carried out to determine the optimal sintering condition. The results show that the thermoelectric properties of pure Ca3Co4O9+δ thick film are comparable to those of cold isostatic pressing (CIP) samples. We found that the maximum power factor was improved by about 67% (to 0.3 mW/m K2) for film with proper silver (Ag) metallic inclusions as compared with 0.18 mW/m K2 for pure Ca3Co4O9+δ film under the same sintering condition of 1223 K for 2 h in air.
    Original languageEnglish
    JournalJournal of Electronic Materials
    Volume41
    Issue number6
    Pages (from-to)1280-1285
    ISSN0361-5235
    DOIs
    Publication statusPublished - 2012

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    Keywords

    • Power factor
    • Thermoelectric oxide
    • Nanoinclusions
    • Misfit-layered cobaltite

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