Mechanistic aspects of ionic reactions in flames

H. Egsgaard; L. Carlsen

doi:10.1016/0165-2370(93)80055-5

Mechanistic aspects of ionic reactions in flames

H. Egsgaard
, L. Carlsen

Research output: Contribution to journal › Conference article › Research › peer-review

Abstract

Some fundamentals of the ion chemistry of flames are summarized. Mechanistic aspects of ionic reactions in flames have been studied using a VG PlasmaQuad, the ICP-system being substituted by a simple quartz burner. Simple hydrocarbon flames as well as sulfur-containing flames have been investigated. The simple hydrocarbon flames are dominated by a series of hydrocarbonic ions and, to a minor extent, protonated oxo-compounds. The introduction of sulfur to the flames leads to significant changes in the ion composition, as sulfur-containing species become dominant. The ability of the technique to study highly reactive species is discussed.

Original language	English
Journal	Journal of Analytical and Applied Pyrolysis
Volume	25
Pages (from-to)	361-370
ISSN	0165-2370
DOIs	https://doi.org/10.1016/0165-2370(93)80055-5
Publication status	Published - 1993
Event	10th International Conference on Fundamental Aspects, Processes and Applications on Pyrolysis - Hamburg, Germany Duration: 27 Sept 1992 → 1 Oct 1992 Conference number: 10

Conference

Conference	10th International Conference on Fundamental Aspects, Processes and Applications on Pyrolysis
Number	10
Country/Territory	Germany
City	Hamburg
Period	27/09/1992 → 01/10/1992

Keywords

Flames
Hydrocarbons
Ionic reactions
Pyrolysis
Sulfur

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title = "Mechanistic aspects of ionic reactions in flames",

abstract = "Some fundamentals of the ion chemistry of flames are summarized. Mechanistic aspects of ionic reactions in flames have been studied using a VG PlasmaQuad, the ICP-system being substituted by a simple quartz burner. Simple hydrocarbon flames as well as sulfur-containing flames have been investigated. The simple hydrocarbon flames are dominated by a series of hydrocarbonic ions and, to a minor extent, protonated oxo-compounds. The introduction of sulfur to the flames leads to significant changes in the ion composition, as sulfur-containing species become dominant. The ability of the technique to study highly reactive species is discussed. ",

keywords = "Forbr{\ae}nding og forgasning, Flames, Hydrocarbons, Ionic reactions, Pyrolysis, Sulfur",

author = "H. Egsgaard and L. Carlsen",

year = "1993",

doi = "10.1016/0165-2370(93)80055-5",

language = "English",

volume = "25",

pages = "361--370",

journal = "Journal of Analytical and Applied Pyrolysis",

issn = "0165-2370",

publisher = "Elsevier",

note = "10th International Conference on Fundamental Aspects, Processes and Applications on Pyrolysis, Pyrolysis 92 ; Conference date: 27-09-1992 Through 01-10-1992",

}

TY - GEN

T1 - Mechanistic aspects of ionic reactions in flames

AU - Egsgaard, H.

AU - Carlsen, L.

N1 - Conference code: 10

PY - 1993

Y1 - 1993

N2 - Some fundamentals of the ion chemistry of flames are summarized. Mechanistic aspects of ionic reactions in flames have been studied using a VG PlasmaQuad, the ICP-system being substituted by a simple quartz burner. Simple hydrocarbon flames as well as sulfur-containing flames have been investigated. The simple hydrocarbon flames are dominated by a series of hydrocarbonic ions and, to a minor extent, protonated oxo-compounds. The introduction of sulfur to the flames leads to significant changes in the ion composition, as sulfur-containing species become dominant. The ability of the technique to study highly reactive species is discussed.

AB - Some fundamentals of the ion chemistry of flames are summarized. Mechanistic aspects of ionic reactions in flames have been studied using a VG PlasmaQuad, the ICP-system being substituted by a simple quartz burner. Simple hydrocarbon flames as well as sulfur-containing flames have been investigated. The simple hydrocarbon flames are dominated by a series of hydrocarbonic ions and, to a minor extent, protonated oxo-compounds. The introduction of sulfur to the flames leads to significant changes in the ion composition, as sulfur-containing species become dominant. The ability of the technique to study highly reactive species is discussed.

KW - Forbrænding og forgasning

KW - Flames

KW - Hydrocarbons

KW - Ionic reactions

KW - Pyrolysis

KW - Sulfur

U2 - 10.1016/0165-2370(93)80055-5

DO - 10.1016/0165-2370(93)80055-5

M3 - Conference article

SN - 0165-2370

VL - 25

SP - 361

EP - 370

JO - Journal of Analytical and Applied Pyrolysis

JF - Journal of Analytical and Applied Pyrolysis

T2 - 10th International Conference on Fundamental Aspects, Processes and Applications on Pyrolysis

Y2 - 27 September 1992 through 1 October 1992

ER -

Mechanistic aspects of ionic reactions in flames

Abstract

Conference

Keywords

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