Mechanism of spontaneous hole formation in thin polymeric films

Kaijia Yu; Henrik K. Rasmussen; José Manuel Román Marín; Ole Hassager

doi:10.1103/PhysRevB.85.024201

Mechanism of spontaneous hole formation in thin polymeric films

Kaijia Yu, Henrik K. Rasmussen, José Manuel Román Marín, Ole Hassager

Research output: Contribution to journal › Journal article › Research › peer-review

441 Downloads (Pure)

Abstract

We show computationally that (molten) thin polymeric film containing nonequilibrium configurations originating from a solvent evaporation may develop holes spontaneously in the molten state, and that they appear delayed. Polymers above the glass transition temperature are liquids where the flow depends solely on the nonequilibrium configurations of the molecules.

Original language	English
Journal	Physical Review B Condensed Matter
Volume	85
Pages (from-to)	024201
ISSN	0163-1829
DOIs	https://doi.org/10.1103/PhysRevB.85.024201
Publication status	Published - 2012

Bibliographical note

Access to Document

10.1103/PhysRevB.85.024201

E024201[1]Final published version, 252 KB

http://prb.aps.org/browse

OpenUrl availability

Full text

Cite this

@article{f65b93f0eeef4b92834b5eee076ed86d,

title = "Mechanism of spontaneous hole formation in thin polymeric films",

abstract = "We show computationally that (molten) thin polymeric film containing nonequilibrium configurations originating from a solvent evaporation may develop holes spontaneously in the molten state, and that they appear delayed. Polymers above the glass transition temperature are liquids where the flow depends solely on the nonequilibrium configurations of the molecules.",

author = "Kaijia Yu and Rasmussen, {Henrik K.} and {Rom{\'a}n Mar{\'i}n}, {Jos{\'e} Manuel} and Ole Hassager",

note = "{\textcopyright}2012 American Physical Society",

year = "2012",

doi = "10.1103/PhysRevB.85.024201",

language = "English",

volume = "85",

pages = "024201",

journal = "Physical Review B Condensed Matter",

issn = "0163-1829",

publisher = "American Physical Society",

}

TY - JOUR

T1 - Mechanism of spontaneous hole formation in thin polymeric films

AU - Yu, Kaijia

AU - Rasmussen, Henrik K.

AU - Román Marín, José Manuel

AU - Hassager, Ole

PY - 2012

Y1 - 2012

N2 - We show computationally that (molten) thin polymeric film containing nonequilibrium configurations originating from a solvent evaporation may develop holes spontaneously in the molten state, and that they appear delayed. Polymers above the glass transition temperature are liquids where the flow depends solely on the nonequilibrium configurations of the molecules.

AB - We show computationally that (molten) thin polymeric film containing nonequilibrium configurations originating from a solvent evaporation may develop holes spontaneously in the molten state, and that they appear delayed. Polymers above the glass transition temperature are liquids where the flow depends solely on the nonequilibrium configurations of the molecules.

U2 - 10.1103/PhysRevB.85.024201

DO - 10.1103/PhysRevB.85.024201

M3 - Journal article

SN - 0163-1829

VL - 85

SP - 024201

JO - Physical Review B Condensed Matter

JF - Physical Review B Condensed Matter

ER -

Mechanism of spontaneous hole formation in thin polymeric films

Abstract

Bibliographical note

Access to Document

OpenUrl availability

Fingerprint

Cite this