Abstract
| Original language | English |
|---|---|
| Title of host publication | Proceedings of the 5th Australian Control Conference (AUCC 2015) |
| Number of pages | 3 |
| Publisher | IEEE |
| Publication date | 2015 |
| Pages | 108-110 |
| ISBN (Print) | 978-1-9221-0770-1 |
| Publication status | Published - 2015 |
| Event | The 5th Australian Control Conference - Gold Coast, Australia Duration: 5 Nov 2015 → 6 Nov 2015 Conference number: 5 http://www.aucc.org.au/AUCC2015/ |
Conference
| Conference | The 5th Australian Control Conference |
|---|---|
| Number | 5 |
| Country | Australia |
| City | Gold Coast |
| Period | 05/11/2015 → 06/11/2015 |
| Internet address |
Cite this
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Manipulation of molecular vibrational motions via pure rotational excitations. / Shu, Chuan-Cun; Henriksen, Niels Engholm.
Proceedings of the 5th Australian Control Conference (AUCC 2015). IEEE, 2015. p. 108-110.Research output: Chapter in Book/Report/Conference proceeding › Article in proceedings › Research › peer-review
TY - GEN
T1 - Manipulation of molecular vibrational motions via pure rotational excitations
AU - Shu, Chuan-Cun
AU - Henriksen, Niels Engholm
PY - 2015
Y1 - 2015
N2 - The coupling between different molecular degrees of freedom plays a decisive role in many quantum phenomena, including electron transfer and energy redistribution. Here, we demonstrate a quantum-mechanical time-dependent simulation to explore how a vibrational motion in a molecule can be affected via the rotation-vibration coupling. Our simulations show that a slow (compared to the vibrational period) rotational excitation leads to a smooth increase in the bond length whereas a fast rotational excitation leads to a non-stationary vibrational motion.
AB - The coupling between different molecular degrees of freedom plays a decisive role in many quantum phenomena, including electron transfer and energy redistribution. Here, we demonstrate a quantum-mechanical time-dependent simulation to explore how a vibrational motion in a molecule can be affected via the rotation-vibration coupling. Our simulations show that a slow (compared to the vibrational period) rotational excitation leads to a smooth increase in the bond length whereas a fast rotational excitation leads to a non-stationary vibrational motion.
M3 - Article in proceedings
SN - 978-1-9221-0770-1
SP - 108
EP - 110
BT - Proceedings of the 5th Australian Control Conference (AUCC 2015)
PB - IEEE
ER -