Abstract
The coupling between different molecular degrees of freedom plays a decisive role in many quantum phenomena, including electron transfer and energy redistribution. Here, we demonstrate a quantum-mechanical time-dependent simulation to explore how a vibrational motion in a molecule can be affected via the rotation-vibration coupling. Our simulations show that a slow (compared to the vibrational period) rotational excitation leads to a smooth increase in the bond length whereas a fast rotational excitation leads to a non-stationary vibrational motion.
Original language | English |
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Title of host publication | Proceedings of the 5th Australian Control Conference (AUCC 2015) |
Number of pages | 3 |
Publisher | IEEE |
Publication date | 2015 |
Pages | 108-110 |
ISBN (Print) | 978-1-9221-0770-1 |
Publication status | Published - 2015 |
Event | The 5th Australian Control Conference - Gold Coast, Australia Duration: 5 Nov 2015 → 6 Nov 2015 Conference number: 5 http://www.aucc.org.au/AUCC2015/ |
Conference
Conference | The 5th Australian Control Conference |
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Number | 5 |
Country | Australia |
City | Gold Coast |
Period | 05/11/2015 → 06/11/2015 |
Internet address |