Magnetic properties of hematite nanoparticles

Franz Bødker, Mikkel Fougt Hansen, Christian Bender Koch, Kim Lefmann, Steen Mørup

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Abstract

The magnetic properties of hematite (alpha-Fe2O3) particles with sizes of about 16 nm have been studied by use of Mossbauer spectroscopy, magnetization measurements, and neutron diffraction. The nanoparticles are weakly ferromagnetic at temperatures at least down to 5 K with a spontaneous magnetization that is only slightly higher than that of weakly ferromagnetic bulk hematite. At T greater than or similar to 100 K the Mossbauer spectra contain a doublet, which is asymmetric due to magnetic relaxation in the presence of an electric field gradient in accordance with the Blume-Tjon model, Simultaneous fitting of series of Mossbauer spectra obtained at temperatures from 5 K to well above the superparamagnetic blocking temperature allowed the estimation of the pre-exponential factor in Neel's expression for the superparamagnetic relaxation time, tau(0) = (6 +/- 4) X 10(-11) s and the magnetic anisotropy energy barrier, E-bm/k = 590+/-(150)(120) K. A lower value of the pre-exponential factor, tau(0) = 1.8+/-X-3.2(1.3) 10(-11) s, and a significantly lower anisotropy energy barrier E-bm(magn)/k = 305 +/- 20 K was derived from simultaneous fitting to ac and de magnetization curves. The difference in the observed energy barriers can be explained by the presence of two different modes of superparamagnetic relaxation which are characteristic of the weakly ferromagnetic phase. One mode involves a rotation of the sublattice magnetization directions in the basal (111) plane, which gives rise to superparamagnetic behavior in both Mossbauer spectroscopy and magnetization measurements. The other mode involves a fluctuation of the net magnetization direction out of the basal plane, which mainly affects the magnetization measurements.
Original languageEnglish
JournalPhysical Review B Condensed Matter
Volume61
Issue number10
Pages (from-to)6826-6838
ISSN0163-1829
DOIs
Publication statusPublished - 2000

Bibliographical note

Copyright (2000) by the American Physical Society.

Keywords

  • OXIDE
  • FE2O3
  • MORIN TRANSITION
  • SUPERPARAMAGNETIC PARTICLES
  • DYNAMICS
  • MOSSBAUER
  • ALPHA-FE2O3 PARTICLES
  • TEMPERATURE

Cite this

Bødker, F., Hansen, M. F., Bender Koch, C., Lefmann, K., & Mørup, S. (2000). Magnetic properties of hematite nanoparticles. Physical Review B Condensed Matter, 61(10), 6826-6838. https://doi.org/10.1103/PhysRevB.61.6826