Magnetic Properties of a Manganese(III) Chain with Monoatomic Bridges: catena-MnF(salen)

Torben Birk; Kasper Steen Pedersen; Stergios Piligkos; Christian Aa Thuesen; Högni Weihe; Jesper Bendix

doi:10.1021/ic2002699

Magnetic Properties of a Manganese(III) Chain with Monoatomic Bridges: catena-MnF(salen)

Torben Birk
, Kasper Steen Pedersen
, Stergios Piligkos
, Christian Aa Thuesen
, Högni Weihe
, Jesper Bendix

University of Copenhagen

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

In the solid state, MnF(salen) forms chains wherein fairly linear fluoride bridges between high-spin Mn^III centers are observed. We interpret the magnetic properties of these chains by use of the classical Fisher model and by use of the high-temperature expansion approach, as well as by exact matrix diagonalization of the spin Hamiltonian, of model rings. In solution, electron paramagnetic resonance shows the chains to be symmetrically cleaved to monomeric MnF(salen).

Original language	English
Journal	Inorganic Chemistry
Volume	50
Issue number	12
Pages (from-to)	5312-5314
ISSN	0020-1669
DOIs	https://doi.org/10.1021/ic2002699
Publication status	Published - 2011
Externally published	Yes

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title = "Magnetic Properties of a Manganese(III) Chain with Monoatomic Bridges: catena-MnF(salen)",

abstract = "In the solid state, MnF(salen) forms chains wherein fairly linear fluoride bridges between high-spin MnIII centers are observed. We interpret the magnetic properties of these chains by use of the classical Fisher model and by use of the high-temperature expansion approach, as well as by exact matrix diagonalization of the spin Hamiltonian, of model rings. In solution, electron paramagnetic resonance shows the chains to be symmetrically cleaved to monomeric MnF(salen).",

author = "Torben Birk and Pedersen, \{Kasper Steen\} and Stergios Piligkos and Thuesen, \{Christian Aa\} and H{\"o}gni Weihe and Jesper Bendix",

year = "2011",

doi = "10.1021/ic2002699",

language = "English",

volume = "50",

pages = "5312--5314",

journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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T1 - Magnetic Properties of a Manganese(III) Chain with Monoatomic Bridges: catena-MnF(salen)

AU - Birk, Torben

AU - Pedersen, Kasper Steen

AU - Piligkos, Stergios

AU - Thuesen, Christian Aa

AU - Weihe, Högni

AU - Bendix, Jesper

PY - 2011

Y1 - 2011

N2 - In the solid state, MnF(salen) forms chains wherein fairly linear fluoride bridges between high-spin MnIII centers are observed. We interpret the magnetic properties of these chains by use of the classical Fisher model and by use of the high-temperature expansion approach, as well as by exact matrix diagonalization of the spin Hamiltonian, of model rings. In solution, electron paramagnetic resonance shows the chains to be symmetrically cleaved to monomeric MnF(salen).

AB - In the solid state, MnF(salen) forms chains wherein fairly linear fluoride bridges between high-spin MnIII centers are observed. We interpret the magnetic properties of these chains by use of the classical Fisher model and by use of the high-temperature expansion approach, as well as by exact matrix diagonalization of the spin Hamiltonian, of model rings. In solution, electron paramagnetic resonance shows the chains to be symmetrically cleaved to monomeric MnF(salen).

U2 - 10.1021/ic2002699

DO - 10.1021/ic2002699

M3 - Journal article

SN - 0020-1669

VL - 50

SP - 5312

EP - 5314

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 12

ER -

Magnetic Properties of a Manganese(III) Chain with Monoatomic Bridges: catena-MnF(salen)

Abstract

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