Mössbauer Emission-Spectra of Impurity Cobalt-57 in a Halide Matrix

A. G. Maddock, A. F. Williams, K. E. Siekierska, J. Fenger

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    The Mössbauer emission spectra of 57Co in low concentrations in KF, NaCl, NaF, LiF, and MgF2, and the effects of doping NaF and LiF with La3+ ions are reported. The monovalent halides all give similar spectra showing a broad single line or a doublet at 2.19mm/s and two overlapping doublets at 0.46 and 0.19 mm/s (w.r.t. metallic iron), although relative intensities vary. Previous Mössbauer and EPR spectroscopic data on these systems are reviewed briefly, and qualitative conclusions drawn on the chemistry of such systems.
    Original languageEnglish
    JournalIPPS physica status solidi (b)
    Volume74
    Issue number1
    Pages (from-to)183-192
    ISSN0370-1972
    DOIs
    Publication statusPublished - 1976

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