Low-temperature side-chain cleavage and decarboxylation of polythiophene esters by acid catalysis

Roar Søndergaard; Kion Norrman; Frederik C Krebs

doi:10.1002/pola.25870

Low-temperature side-chain cleavage and decarboxylation of polythiophene esters by acid catalysis

Roar Søndergaard, Kion Norrman, Frederik C Krebs

Research output: Contribution to journal › Journal article › peer-review

Abstract

Solubility switching of polymers is very useful in thin layer processing of conjugated polymers, as it allows for multilayer processing and increases the stability of the polymer. Acid catalyzed thermocleavage of ester groups from thiophene polymers carrying primary, secondary, and tertiary substituents have been examined by TGA‐MS using different sulphonic acids. A substantial lowering of the cleavage temperature is observed, and the ester cleavage can even be performed in situ on roll‐to‐roll‐coated films on polyethylene terephthalate (PET). © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012

Original language	English
Journal	Journal of Polymer Science. Part A, Polymer Chemistry
Volume	50
Issue number	6
Pages (from-to)	1127-1132
ISSN	0887-624X
DOIs	https://doi.org/10.1002/pola.25870
Publication status	Published - 2012

Bibliographical note

The authors thank the Danish Strategic Research Council (DSF
2104-07-0022) for financial support.

Keywords

Tertiary ester
Thermogravimetric analysis (TGA)
Primary ester
Conducting polymers
Thermocleavage
Polythiophene ester
Low temperature
Secondary ester
Solubility switching
Ester cleavage
Decarboxylation
Acid catalysis
Catalysis

Access to Document

10.1002/pola.25870

1 Finished

Polymer Solar Cells for Solar Energy Conversion
Krebs, F. C.
01/01/2008 → 31/12/2013
Project: Research

Cite this

@article{ee1b350394e7486586f23d275380590c,

title = "Low-temperature side-chain cleavage and decarboxylation of polythiophene esters by acid catalysis",

abstract = "Solubility switching of polymers is very useful in thin layer processing of conjugated polymers, as it allows for multilayer processing and increases the stability of the polymer. Acid catalyzed thermocleavage of ester groups from thiophene polymers carrying primary, secondary, and tertiary substituents have been examined by TGA‐MS using different sulphonic acids. A substantial lowering of the cleavage temperature is observed, and the ester cleavage can even be performed in situ on roll‐to‐roll‐coated films on polyethylene terephthalate (PET). {\textcopyright} 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012",

keywords = "Tertiary ester, Thermogravimetric analysis (TGA), Primary ester, Conducting polymers, Thermocleavage, Polythiophene ester, Low temperature, Secondary ester, Solubility switching, Ester cleavage, Decarboxylation, Acid catalysis, Catalysis",

author = "Roar S{\o}ndergaard and Kion Norrman and Krebs, {Frederik C}",

note = "The authors thank the Danish Strategic Research Council (DSF 2104-07-0022) for financial support.",

year = "2012",

doi = "10.1002/pola.25870",

language = "English",

volume = "50",

pages = "1127--1132",

journal = "Journal of Polymer Science. Part A, Polymer Chemistry",

issn = "0887-624X",

publisher = "JohnWiley & Sons, Inc.",

number = "6",

}

TY - JOUR

T1 - Low-temperature side-chain cleavage and decarboxylation of polythiophene esters by acid catalysis

AU - Søndergaard, Roar

AU - Norrman, Kion

AU - Krebs, Frederik C

N1 - The authors thank the Danish Strategic Research Council (DSF 2104-07-0022) for financial support.

PY - 2012

Y1 - 2012

N2 - Solubility switching of polymers is very useful in thin layer processing of conjugated polymers, as it allows for multilayer processing and increases the stability of the polymer. Acid catalyzed thermocleavage of ester groups from thiophene polymers carrying primary, secondary, and tertiary substituents have been examined by TGA‐MS using different sulphonic acids. A substantial lowering of the cleavage temperature is observed, and the ester cleavage can even be performed in situ on roll‐to‐roll‐coated films on polyethylene terephthalate (PET). © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012

AB - Solubility switching of polymers is very useful in thin layer processing of conjugated polymers, as it allows for multilayer processing and increases the stability of the polymer. Acid catalyzed thermocleavage of ester groups from thiophene polymers carrying primary, secondary, and tertiary substituents have been examined by TGA‐MS using different sulphonic acids. A substantial lowering of the cleavage temperature is observed, and the ester cleavage can even be performed in situ on roll‐to‐roll‐coated films on polyethylene terephthalate (PET). © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012

KW - Tertiary ester

KW - Thermogravimetric analysis (TGA)

KW - Primary ester

KW - Conducting polymers

KW - Thermocleavage

KW - Polythiophene ester

KW - Low temperature

KW - Secondary ester

KW - Solubility switching

KW - Ester cleavage

KW - Decarboxylation

KW - Acid catalysis

KW - Catalysis

U2 - 10.1002/pola.25870

DO - 10.1002/pola.25870

M3 - Journal article

VL - 50

SP - 1127

EP - 1132

JO - Journal of Polymer Science. Part A, Polymer Chemistry

JF - Journal of Polymer Science. Part A, Polymer Chemistry

SN - 0887-624X

IS - 6

ER -

Low-temperature side-chain cleavage and decarboxylation of polythiophene esters by acid catalysis

Abstract

Bibliographical note

Keywords

Access to Document

Fingerprint

Projects

Polymer Solar Cells for Solar Energy Conversion

Cite this