Long term testing of start–stop cycles on high temperature PEM fuel cell stack

Arvind Kannan, Alexander Kabza, Joachim Scholta

Research output: Contribution to journalJournal articleResearchpeer-review

481 Downloads (Pure)

Abstract

A PEM fuel cell with an operating temperature above 100 °C is desired for increasing the kinetics of reactions, reduced sensitivity to impurities of the fuel, as well as for the reduction of the requirements on thermal and water management systems. High Temperature Polymer Electrolyte Membrane Fuel Cells (HT-PEMFC) can effectively be combined with CHP systems to offer a simple system design and higher overall system efficiencies. For HT-PEMFC systems, the development of elaborated start/stop strategies is essential in mitigation of fuel cell degradation during these events. A 5 cell co-flow stack is assembled with BASF P1100W membrane electrode assembly (MEA) with an active area of 163.5 cm2. Continuous operation and more than 1500 start stop cycles have been performed in order to study the degradation effects of both continuous operation and of repeated start stops using a protective start–stop algorithm, which is designed to avoid the formation of aggressive cell potentials. The repeated use of this procedure led to a degradation of 26 μV/cycle at a current density of 0.25 A cm−2 and 11 μV/cycle at a current density of 0.03 A cm−2. At open circuit voltage (OCV), a higher degradation rate of 133 μV/cycle was observed.
Original languageEnglish
JournalJournal of Power Sources
Volume277
Pages (from-to)312–316
ISSN0378-7753
DOIs
Publication statusPublished - 2015
Externally publishedYes

Keywords

  • High temperature PEM fuel cell
  • PBI/H3PO4
  • Performance degradation
  • Start-stop
  • Long term testing

Fingerprint Dive into the research topics of 'Long term testing of start–stop cycles on high temperature PEM fuel cell stack'. Together they form a unique fingerprint.

Cite this