Line widths in nitroxides

Finn Radner; Carl Johan Hersvall; André Rassat; Jan Henrik Ardenkjær-Larsen; Serge Gambarelli; Daniel Jaouen

doi:10.1163/156856796X00610

Line widths in nitroxides

Finn Radner, Carl Johan Hersvall, André Rassat, Jan Henrik Ardenkjær-Larsen, Serge Gambarelli, Daniel Jaouen

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The 2,5-di-tert-butyl-3,4-dimethoxycarbonyl-pyrryloxyl radical has the small est line-width and the smallest nitrogen hyperfine splitting reported for a stable nitroxide. The influence of long range proton splittings was shown by selective and total deuteriation. As expected on theoretical grounds, line widths and nitrogen hyperfine splitting are correlated.

Original language	English
Journal	Research on Chemical Intermediates
Volume	22
Issue number	5
Pages (from-to)	417-425
ISSN	0922-6168
DOIs	https://doi.org/10.1163/156856796X00610
Publication status	Published - 1996
Externally published	Yes

Access to Document

10.1163/156856796X00610

OpenUrl availability

Full text

Cite this

@article{b3c7a0801e2440b399c9b3e6793e130d,

title = "Line widths in nitroxides",

abstract = "The 2,5-di-tert-butyl-3,4-dimethoxycarbonyl-pyrryloxyl radical has the small est line-width and the smallest nitrogen hyperfine splitting reported for a stable nitroxide. The influence of long range proton splittings was shown by selective and total deuteriation. As expected on theoretical grounds, line widths and nitrogen hyperfine splitting are correlated.",

author = "Finn Radner and Hersvall, {Carl Johan} and Andr{\'e} Rassat and Ardenkj{\ae}r-Larsen, {Jan Henrik} and Serge Gambarelli and Daniel Jaouen",

year = "1996",

doi = "10.1163/156856796X00610",

language = "English",

volume = "22",

pages = "417--425",

journal = "Research on Chemical Intermediates",

issn = "0922-6168",

publisher = "Springer Netherlands",

number = "5",

}

TY - JOUR

T1 - Line widths in nitroxides

AU - Radner, Finn

AU - Hersvall, Carl Johan

AU - Rassat, André

AU - Ardenkjær-Larsen, Jan Henrik

AU - Gambarelli, Serge

AU - Jaouen, Daniel

PY - 1996

Y1 - 1996

N2 - The 2,5-di-tert-butyl-3,4-dimethoxycarbonyl-pyrryloxyl radical has the small est line-width and the smallest nitrogen hyperfine splitting reported for a stable nitroxide. The influence of long range proton splittings was shown by selective and total deuteriation. As expected on theoretical grounds, line widths and nitrogen hyperfine splitting are correlated.

AB - The 2,5-di-tert-butyl-3,4-dimethoxycarbonyl-pyrryloxyl radical has the small est line-width and the smallest nitrogen hyperfine splitting reported for a stable nitroxide. The influence of long range proton splittings was shown by selective and total deuteriation. As expected on theoretical grounds, line widths and nitrogen hyperfine splitting are correlated.

U2 - 10.1163/156856796X00610

DO - 10.1163/156856796X00610

M3 - Journal article

SN - 0922-6168

VL - 22

SP - 417

EP - 425

JO - Research on Chemical Intermediates

JF - Research on Chemical Intermediates

IS - 5

ER -

Line widths in nitroxides

Abstract

Access to Document

OpenUrl availability

Fingerprint

Cite this