The technique of pulse radiolysis combined with transient ultraviolet absorption spectrophotometry has been employed in spectrokinetic studies of shortlived free radical intermediates of importance in combustion. Various source reactions for vinyl, propargyl and carboxyl radicals have been investigated and the UV-spektre of these radicals have been recorded. The spectral features have been utilized in kinetic studies of the self-reactions of the radicals and the reactions with oxygen. Kinetic results on the reaction NO + NH2 are also reported.
|Place of Publication||Roskilde|
|Publisher||Risø National Laboratory|
|Number of pages||54|
|Publication status||Published - 1988|