Kinetics and Mechanisms of Elementary Chemical Processes of Importance in Combustion

J. Munk; Palle Bjørn Pagsberg; E. Ratajczak; B. Sztuba; A. Sillesen

Kinetics and Mechanisms of Elementary Chemical Processes of Importance in Combustion

J. Munk, Palle Bjørn Pagsberg, E. Ratajczak, B. Sztuba, A. Sillesen

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Abstract

The technique of pulse radiolysis combined with transient ultraviolet absorption spectrophotometry has been employed in spectrokinetic studies of shortlived free radical intermediates of importance in combustion. Various source reactions for vinyl, propargyl and carboxyl radicals have been investigated and the UV-spektre of these radicals have been recorded. The spectral features have been utilized in kinetic studies of the self-reactions of the radicals and the reactions with oxygen. Kinetic results on the reaction NO + NH2 are also reported.

Original language	English

Place of Publication	Roskilde
Publisher	Risø National Laboratory
Number of pages	54
ISBN (Print)	87-550-1394-5
Publication status	Published - 1988

Series	Risø-M
Number	2688
ISSN	0418-6435

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Risø-M-2688

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T1 - Kinetics and Mechanisms of Elementary Chemical Processes of Importance in Combustion

AU - Munk, J.

AU - Pagsberg, Palle Bjørn

AU - Ratajczak, E.

AU - Sztuba, B.

AU - Sillesen, A.

PY - 1988

Y1 - 1988

N2 - The technique of pulse radiolysis combined with transient ultraviolet absorption spectrophotometry has been employed in spectrokinetic studies of shortlived free radical intermediates of importance in combustion. Various source reactions for vinyl, propargyl and carboxyl radicals have been investigated and the UV-spektre of these radicals have been recorded. The spectral features have been utilized in kinetic studies of the self-reactions of the radicals and the reactions with oxygen. Kinetic results on the reaction NO + NH2 are also reported.

AB - The technique of pulse radiolysis combined with transient ultraviolet absorption spectrophotometry has been employed in spectrokinetic studies of shortlived free radical intermediates of importance in combustion. Various source reactions for vinyl, propargyl and carboxyl radicals have been investigated and the UV-spektre of these radicals have been recorded. The spectral features have been utilized in kinetic studies of the self-reactions of the radicals and the reactions with oxygen. Kinetic results on the reaction NO + NH2 are also reported.

KW - Risø-M-2688

M3 - Report

SN - 87-550-1394-5

T3 - Risø-M

BT - Kinetics and Mechanisms of Elementary Chemical Processes of Importance in Combustion

PB - Risø National Laboratory

CY - Roskilde

ER -

Kinetics and Mechanisms of Elementary Chemical Processes of Importance in Combustion

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