Isotope Effects in the Bonds of beta-CrOOH and beta-CrOOD

A. Nørlund Christensen, P. Hansen, M. S. Lehmann

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    Samples of orthorhombic chromium oxide hydroxide, beta -CrOOH, and the deuterated compound, beta -CrOOD, were prepared hydrothermally. The crystal structures were determined by powder profile refinement technique using neutron diffraction data. Unit cells are: beta -CrOOH: a equals 4. 862(2) A, b equals 4. 298(a) A, c equals 2. 995(1) A; beta -CrOOD: a equals 4. 873(5) A, b equals 4. 332(7) A, c equals 2. 963(2) A, with Z equals 2. The space group is P2//1nm or Pnnm.
    Original languageEnglish
    JournalJournal of Solid State Chemistry
    Volume19
    Issue number3
    Pages (from-to)299-304
    ISSN0022-4596
    DOIs
    Publication statusPublished - 1976

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