Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High-Temperature Polymer Electrolyte Membrane Fuel Cells

Yi Cheng, Shuai He, Shanfu Lu*, Jean-Pierre Veder, Bernt Johannessen, Lars Thomsen, Martin Saunders, Thomas Becker, Roland De Marco, Qingfeng Li, Shi-ze Yang, San Ping Jiang

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

70 Downloads (Pure)

Abstract

Iron single atom catalysts (Fe SACs) are the best‐known nonprecious metal (NPM) catalysts for the oxygen reduction reaction (ORR) of polymer electrolyte membrane fuel cells (PEMFCs), but their practical application has been constrained by the low Fe SACs loading (<2 wt%). Here, a one‐pot pyrolysis method is reported for the synthesis of iron single atoms on graphene (FeSA‐G) with a high Fe SAC loading of ≈7.7 ± 1.3 wt%. The as‐synthesized FeSA‐G shows an onset potential of 0.950 V and a half‐wave potential of 0.804 V in acid electrolyte for the ORR, similar to that of Pt/C catalysts but with a much higher stability and higher phosphate anion tolerance. High temperature SiO2 nanoparticle‐doped phosphoric acid/polybenzimidazole (PA/PBI/SiO2) composite membrane cells utilizing a FeSA‐G cathode with Fe SAC loading of 0.3 mg cm−2 delivers a peak power density of 325 mW cm−2 at 230 °C, better than 313 mW cm−2 obtained on the cell with a Pt/C cathode at a Pt loading of 1 mg cm−2. The cell with FeSA‐G cathode exhibits superior stability at 230 °C, as compared to that with Pt/C cathode. Our results provide a new approach to developing practical NPM catalysts to replace Pt‐based catalysts for fuel cells.
Original languageEnglish
Article number1802066
JournalAdvanced Science
Volume6
Issue number10
Number of pages8
ISSN2198-3844
DOIs
Publication statusPublished - 2019

Keywords

  • High loading
  • High temperature polymer electrolyte membrane fuel cells
  • Iron single atom catalysis
  • Nonprecious metal catalysts
  • Oxygen reduction reaction

Cite this

Cheng, Y., He, S., Lu, S., Veder, J-P., Johannessen, B., Thomsen, L., ... Jiang, S. P. (2019). Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High-Temperature Polymer Electrolyte Membrane Fuel Cells. Advanced Science, 6(10), [1802066]. https://doi.org/10.1002/advs.201802066
Cheng, Yi ; He, Shuai ; Lu, Shanfu ; Veder, Jean-Pierre ; Johannessen, Bernt ; Thomsen, Lars ; Saunders, Martin ; Becker, Thomas ; De Marco, Roland ; Li, Qingfeng ; Yang, Shi-ze ; Jiang, San Ping. / Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High-Temperature Polymer Electrolyte Membrane Fuel Cells. In: Advanced Science. 2019 ; Vol. 6, No. 10.
@article{9a1f5372cc1e43f0b01323c1b46a7175,
title = "Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High-Temperature Polymer Electrolyte Membrane Fuel Cells",
abstract = "Iron single atom catalysts (Fe SACs) are the best‐known nonprecious metal (NPM) catalysts for the oxygen reduction reaction (ORR) of polymer electrolyte membrane fuel cells (PEMFCs), but their practical application has been constrained by the low Fe SACs loading (<2 wt{\%}). Here, a one‐pot pyrolysis method is reported for the synthesis of iron single atoms on graphene (FeSA‐G) with a high Fe SAC loading of ≈7.7 ± 1.3 wt{\%}. The as‐synthesized FeSA‐G shows an onset potential of 0.950 V and a half‐wave potential of 0.804 V in acid electrolyte for the ORR, similar to that of Pt/C catalysts but with a much higher stability and higher phosphate anion tolerance. High temperature SiO2 nanoparticle‐doped phosphoric acid/polybenzimidazole (PA/PBI/SiO2) composite membrane cells utilizing a FeSA‐G cathode with Fe SAC loading of 0.3 mg cm−2 delivers a peak power density of 325 mW cm−2 at 230 °C, better than 313 mW cm−2 obtained on the cell with a Pt/C cathode at a Pt loading of 1 mg cm−2. The cell with FeSA‐G cathode exhibits superior stability at 230 °C, as compared to that with Pt/C cathode. Our results provide a new approach to developing practical NPM catalysts to replace Pt‐based catalysts for fuel cells.",
keywords = "High loading, High temperature polymer electrolyte membrane fuel cells, Iron single atom catalysis, Nonprecious metal catalysts, Oxygen reduction reaction",
author = "Yi Cheng and Shuai He and Shanfu Lu and Jean-Pierre Veder and Bernt Johannessen and Lars Thomsen and Martin Saunders and Thomas Becker and {De Marco}, Roland and Qingfeng Li and Shi-ze Yang and Jiang, {San Ping}",
year = "2019",
doi = "10.1002/advs.201802066",
language = "English",
volume = "6",
journal = "Advanced Science",
issn = "2198-3844",
publisher = "Wiley",
number = "10",

}

Cheng, Y, He, S, Lu, S, Veder, J-P, Johannessen, B, Thomsen, L, Saunders, M, Becker, T, De Marco, R, Li, Q, Yang, S & Jiang, SP 2019, 'Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High-Temperature Polymer Electrolyte Membrane Fuel Cells', Advanced Science, vol. 6, no. 10, 1802066. https://doi.org/10.1002/advs.201802066

Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High-Temperature Polymer Electrolyte Membrane Fuel Cells. / Cheng, Yi; He, Shuai; Lu, Shanfu; Veder, Jean-Pierre; Johannessen, Bernt; Thomsen, Lars; Saunders, Martin; Becker, Thomas; De Marco, Roland; Li, Qingfeng; Yang, Shi-ze; Jiang, San Ping.

In: Advanced Science, Vol. 6, No. 10, 1802066, 2019.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High-Temperature Polymer Electrolyte Membrane Fuel Cells

AU - Cheng, Yi

AU - He, Shuai

AU - Lu, Shanfu

AU - Veder, Jean-Pierre

AU - Johannessen, Bernt

AU - Thomsen, Lars

AU - Saunders, Martin

AU - Becker, Thomas

AU - De Marco, Roland

AU - Li, Qingfeng

AU - Yang, Shi-ze

AU - Jiang, San Ping

PY - 2019

Y1 - 2019

N2 - Iron single atom catalysts (Fe SACs) are the best‐known nonprecious metal (NPM) catalysts for the oxygen reduction reaction (ORR) of polymer electrolyte membrane fuel cells (PEMFCs), but their practical application has been constrained by the low Fe SACs loading (<2 wt%). Here, a one‐pot pyrolysis method is reported for the synthesis of iron single atoms on graphene (FeSA‐G) with a high Fe SAC loading of ≈7.7 ± 1.3 wt%. The as‐synthesized FeSA‐G shows an onset potential of 0.950 V and a half‐wave potential of 0.804 V in acid electrolyte for the ORR, similar to that of Pt/C catalysts but with a much higher stability and higher phosphate anion tolerance. High temperature SiO2 nanoparticle‐doped phosphoric acid/polybenzimidazole (PA/PBI/SiO2) composite membrane cells utilizing a FeSA‐G cathode with Fe SAC loading of 0.3 mg cm−2 delivers a peak power density of 325 mW cm−2 at 230 °C, better than 313 mW cm−2 obtained on the cell with a Pt/C cathode at a Pt loading of 1 mg cm−2. The cell with FeSA‐G cathode exhibits superior stability at 230 °C, as compared to that with Pt/C cathode. Our results provide a new approach to developing practical NPM catalysts to replace Pt‐based catalysts for fuel cells.

AB - Iron single atom catalysts (Fe SACs) are the best‐known nonprecious metal (NPM) catalysts for the oxygen reduction reaction (ORR) of polymer electrolyte membrane fuel cells (PEMFCs), but their practical application has been constrained by the low Fe SACs loading (<2 wt%). Here, a one‐pot pyrolysis method is reported for the synthesis of iron single atoms on graphene (FeSA‐G) with a high Fe SAC loading of ≈7.7 ± 1.3 wt%. The as‐synthesized FeSA‐G shows an onset potential of 0.950 V and a half‐wave potential of 0.804 V in acid electrolyte for the ORR, similar to that of Pt/C catalysts but with a much higher stability and higher phosphate anion tolerance. High temperature SiO2 nanoparticle‐doped phosphoric acid/polybenzimidazole (PA/PBI/SiO2) composite membrane cells utilizing a FeSA‐G cathode with Fe SAC loading of 0.3 mg cm−2 delivers a peak power density of 325 mW cm−2 at 230 °C, better than 313 mW cm−2 obtained on the cell with a Pt/C cathode at a Pt loading of 1 mg cm−2. The cell with FeSA‐G cathode exhibits superior stability at 230 °C, as compared to that with Pt/C cathode. Our results provide a new approach to developing practical NPM catalysts to replace Pt‐based catalysts for fuel cells.

KW - High loading

KW - High temperature polymer electrolyte membrane fuel cells

KW - Iron single atom catalysis

KW - Nonprecious metal catalysts

KW - Oxygen reduction reaction

U2 - 10.1002/advs.201802066

DO - 10.1002/advs.201802066

M3 - Journal article

VL - 6

JO - Advanced Science

JF - Advanced Science

SN - 2198-3844

IS - 10

M1 - 1802066

ER -