Abstract
Ionic liquids (ILs) have been applied as recyclable reaction media in the decarbonylation of aldehydes in the presence of a rhodium-phosphine complex catalyst. The performance of several new catalytic systems based on imidazolium-based ILs and [Rh(dppp)2]Cl (dppp: 1,3-diphenylphosphinopropane) were excellent in the decarbonylation of both aromatic and aliphatic aldehydes providing >99 yield of benzenes and alkanes, respectively. The catalytic performance depended, however, strongly on the employed IL and its thermal stability. In addition, the ILs afforded good catalyst immobilization as well as a biphasic system with the product allowing recovery and reuse of the employed catalyst.
| Original language | English |
|---|---|
| Journal | RSC Advances |
| Volume | 4 |
| Issue number | 102 |
| Pages (from-to) | 58151-58155 |
| ISSN | 2046-2069 |
| DOIs | |
| Publication status | Published - 2014 |
Keywords
- Aldehydes
- Aromatic compounds
- Catalysts
- Phosphorus compounds
- Rhodium
- Rhodium compounds
- Aliphatic aldehydes
- Biphasic systems
- Catalyst immobilization
- Catalytic performance
- Decarbonylations
- Imidazolium-based
- Ionic liquid (ils)
- Phosphine complex
- Ionic liquids