Interlaboratory indoor ageing of roll-to-roll and spin coated organic photovoltaic devices: Testing the ISOS tests

Suren A. Gevorgyan, Michael Corazza, Morten Vesterager Madsen, Giorgio Bardizza, Alberto Pozza, Harald Müllejans, James C. Blakesley, George F.A. Dibb, Fernando A. Castro, Juan F. Trigo, Cecilia M. Guillén, Jose R. Herrero, Pasquale Morvillo, Maria G. Maglione, Carla Minarini, Francesco Roca, Stéphane Cros, Caroline Seraine, Chun H. Law, Pabitra S. TuladharJames R. Durrant, Frederik C Krebs

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

The inter-comparability of ageing of organic photovoltaic (OPV) technologies in dark is addressed. Four primary factors that affect the reproducibility of the ageing rate determination and inter-comparison are discussed: production/encapsulation of the samples, current–voltage (IV) characterization, testing conditions for ageing and lifetime determination from a decay curve.Results of inter-laboratory ageing studies of roll-to-roll and spin coated samples with correspondingly flexible plastic packaging and glass stored in dark conditions among 7 laboratories are presented. ISOS test conditions, proposed recently as guiding protocols for testing OPV stability, are applied in the study. The reproducibility of the performance versus the production and encapsulation techniques is firstly studied. The results reveal a significant improvement in the reproducibility when going from manual spin coating to roll-to-roll production. Furthermore, the reproducibility of current–voltage (IV) measurement and preconditioning (light soaking treatments) are addressed. Additionally, the inter-comparison of the degradation rates of the samples aged under three different dark test conditions (ambient, dry/heat, damp heat) reported by different groups are analyzed revealing a reasonable agreement. Finally, a logarithmic diagram for OPV lifetime associated with common time units is proposed that allows conveniently categorizing and intercomparing the stability performance of different samples aged under different test conditions.
Original languageEnglish
JournalPolymer Degradation and Stability
Volume109
Pages (from-to)162-170
Number of pages9
ISSN0141-3910
DOIs
Publication statusPublished - 2014

Keywords

  • Organic photovoltaic
  • Interlaboratory study
  • Stability
  • Degradation
  • Lifetime reporting

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