Insights into Kinetics of Methane Hydrate Formation in the Presence of Surfactants

Ashok Pandey, Yousef Jouljamal Daas, Nicolas von Solms*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

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Abstract

Sodium dodecyl sulfate (SDS) is a well-known surfactant, which can accelerate methane hydrate formation. In this work, methane hydrate formation kinetics were studied in the presence of SDS using a rocking cell apparatus in both temperature-ramping and isothermal modes. Ramping and isothermal experiments together suggest that SDS concentration plays a vital role in the formation kinetics of methane hydrate, both in terms of induction time and of final gas uptake. There is a trade-off between growth rate and gas uptake for the optimum SDS concentration, such that an increase in SDS concentration decreases the induction time but also decreases the gas storage capacity for a given volume. The experiments also confirm the potential use of the rocking cell for investigating hydrate promoters. It allows multiple systems to run in parallel at similar experimental temperature and pressure conditions, thus shortening the total experimentation time. Understanding methane hydrate formation and storage using SDS can facilitate large-scale applications such as natural gas storage and transportation
Original languageEnglish
Article number598
JournalProcesses
Volume7
Issue number9
Number of pages19
ISSN2227-9717
DOIs
Publication statusPublished - 2019

Keywords

  • Methane hydrate
  • Rocking cell
  • Sodium dodecyl sulfate
  • Induction time
  • Gas uptake

Cite this

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title = "Insights into Kinetics of Methane Hydrate Formation in the Presence of Surfactants",
abstract = "Sodium dodecyl sulfate (SDS) is a well-known surfactant, which can accelerate methane hydrate formation. In this work, methane hydrate formation kinetics were studied in the presence of SDS using a rocking cell apparatus in both temperature-ramping and isothermal modes. Ramping and isothermal experiments together suggest that SDS concentration plays a vital role in the formation kinetics of methane hydrate, both in terms of induction time and of final gas uptake. There is a trade-off between growth rate and gas uptake for the optimum SDS concentration, such that an increase in SDS concentration decreases the induction time but also decreases the gas storage capacity for a given volume. The experiments also confirm the potential use of the rocking cell for investigating hydrate promoters. It allows multiple systems to run in parallel at similar experimental temperature and pressure conditions, thus shortening the total experimentation time. Understanding methane hydrate formation and storage using SDS can facilitate large-scale applications such as natural gas storage and transportation",
keywords = "Methane hydrate, Rocking cell, Sodium dodecyl sulfate, Induction time, Gas uptake",
author = "Ashok Pandey and {Jouljamal Daas}, Yousef and Solms, {Nicolas von}",
year = "2019",
doi = "10.3390/pr7090598",
language = "English",
volume = "7",
journal = "Processes",
issn = "2227-9717",
publisher = "M D P I AG",
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}

Insights into Kinetics of Methane Hydrate Formation in the Presence of Surfactants. / Pandey, Ashok; Jouljamal Daas, Yousef ; Solms, Nicolas von.

In: Processes, Vol. 7, No. 9, 598, 2019.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Insights into Kinetics of Methane Hydrate Formation in the Presence of Surfactants

AU - Pandey, Ashok

AU - Jouljamal Daas, Yousef

AU - Solms, Nicolas von

PY - 2019

Y1 - 2019

N2 - Sodium dodecyl sulfate (SDS) is a well-known surfactant, which can accelerate methane hydrate formation. In this work, methane hydrate formation kinetics were studied in the presence of SDS using a rocking cell apparatus in both temperature-ramping and isothermal modes. Ramping and isothermal experiments together suggest that SDS concentration plays a vital role in the formation kinetics of methane hydrate, both in terms of induction time and of final gas uptake. There is a trade-off between growth rate and gas uptake for the optimum SDS concentration, such that an increase in SDS concentration decreases the induction time but also decreases the gas storage capacity for a given volume. The experiments also confirm the potential use of the rocking cell for investigating hydrate promoters. It allows multiple systems to run in parallel at similar experimental temperature and pressure conditions, thus shortening the total experimentation time. Understanding methane hydrate formation and storage using SDS can facilitate large-scale applications such as natural gas storage and transportation

AB - Sodium dodecyl sulfate (SDS) is a well-known surfactant, which can accelerate methane hydrate formation. In this work, methane hydrate formation kinetics were studied in the presence of SDS using a rocking cell apparatus in both temperature-ramping and isothermal modes. Ramping and isothermal experiments together suggest that SDS concentration plays a vital role in the formation kinetics of methane hydrate, both in terms of induction time and of final gas uptake. There is a trade-off between growth rate and gas uptake for the optimum SDS concentration, such that an increase in SDS concentration decreases the induction time but also decreases the gas storage capacity for a given volume. The experiments also confirm the potential use of the rocking cell for investigating hydrate promoters. It allows multiple systems to run in parallel at similar experimental temperature and pressure conditions, thus shortening the total experimentation time. Understanding methane hydrate formation and storage using SDS can facilitate large-scale applications such as natural gas storage and transportation

KW - Methane hydrate

KW - Rocking cell

KW - Sodium dodecyl sulfate

KW - Induction time

KW - Gas uptake

U2 - 10.3390/pr7090598

DO - 10.3390/pr7090598

M3 - Journal article

VL - 7

JO - Processes

JF - Processes

SN - 2227-9717

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M1 - 598

ER -