Inner Sphere and Outer Sphere Electron Transfer to Methyl
                Iodide. Deuterium and 13C Kinetic Isotope Effects

Torkil Holm; Ingolf Crossland

Inner Sphere and Outer Sphere Electron Transfer to Methyl Iodide. Deuterium and 13C Kinetic Isotope Effects

Torkil Holm, Ingolf Crossland

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Deuterium and 13C kinetic isotope effects (KIEs) have been determined for the conversion of methyl iodide into methyl radical via inner sphere ET (electron transfer) and via outer sphere ET. The alfa-deuterium KIE was found to be very high for in

Original language	English
Journal	Acta Chem. Scand.
Volume	50
Pages (from-to)	90-93
Publication status	Published - 1996

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title = "Inner Sphere and Outer Sphere Electron Transfer to Methyl Iodide. Deuterium and 13C Kinetic Isotope Effects",

abstract = "Deuterium and 13C kinetic isotope effects (KIEs) have been determined for the conversion of methyl iodide into methyl radical via inner sphere ET (electron transfer) and via outer sphere ET. The alfa-deuterium KIE was found to be very high for in",

author = "Torkil Holm and Ingolf Crossland",

year = "1996",

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pages = "90--93",

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T1 - Inner Sphere and Outer Sphere Electron Transfer to Methyl Iodide. Deuterium and 13C Kinetic Isotope Effects

AU - Holm, Torkil

AU - Crossland, Ingolf

PY - 1996

Y1 - 1996

N2 - Deuterium and 13C kinetic isotope effects (KIEs) have been determined for the conversion of methyl iodide into methyl radical via inner sphere ET (electron transfer) and via outer sphere ET. The alfa-deuterium KIE was found to be very high for in

AB - Deuterium and 13C kinetic isotope effects (KIEs) have been determined for the conversion of methyl iodide into methyl radical via inner sphere ET (electron transfer) and via outer sphere ET. The alfa-deuterium KIE was found to be very high for in

M3 - Journal article

VL - 50

SP - 90

EP - 93

JO - Acta Chem. Scand.

JF - Acta Chem. Scand.

ER -