Abstract
Gas phase carburisation of titanium in CH 4 atmosphere was carried out in a thermogravimetric analyser. The analysis revealed the formation of TiC phase embedded in an amorphous carbon (a-C) matrix. Raman scattering investigation revealed the evolution of two separate peaks corresponding to D and G band vibrational modes in a hexagonal sp 2 phase of the graphite-like structure. The tribological properties of this coating relied significantly on the relative extent of D and G band modes with the evolution of TiC phase. A sharp transition of friction from lower to higher value was observed due to the wearing out of tribolubricant phases of TiC with disordered graphite-like structure present in the a-C matrix. In case of thicker coating, a lower regime of friction was observed with longer wear distances. © 2011 W. S. Maney & Son Ltd.
| Original language | English |
|---|---|
| Journal | Tribology - Materials, Surfaces & Interfaces |
| Volume | 5 |
| Issue number | 4 |
| Pages (from-to) | 172-176 |
| ISSN | 1751-5831 |
| DOIs | |
| Publication status | Published - 2011 |
| Externally published | Yes |
Keywords
- Composite coatings
- Friction
- TiC/a-C
- Wear
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