Influence of porous support structure and the possible presence of active layer defects on FO membrane behaviour

Mattia Giagnorio, Begüm Tanis, Claus Hélix-Nielsen, Fynn Jerome Aschmoneit*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

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Abstract

In forward osmosis, defects on the selective active layer and changes in the porous structure of the support layer can be detrimental factors affecting the membrane performance. This study focuses on the impacts of (i) the possible presence of defects and (ii) the changes in pore structures on the water flux and membrane selectivity via computational fluid dynamics analyses. Results suggest that diffusion of the draw solute through the support layer, i.e. internal concentration polarization, can be strongly enhanced or reduced by widening or narrowing the shape of the pore, respectively, while no significant effect on water permeation can be associated with the change in draw solution cross-flow velocity or in the loss of draw solute during filtration. Interestingly, defects within the active layer may affect the water flux exponentially as function of the defect size, suggesting the presence of a threshold below which the convective passage of contaminated water flux through the defect is not affecting the membrane productivity. Moreover, the presence of defects may not be a detrimental factor for membrane operating with high nominal rejection (> 90%) and low percentage of defected area (< 1%).
Original languageEnglish
Article number125182
JournalSeparation and Purification Technology
Volume330
Number of pages9
ISSN1383-5866
DOIs
Publication statusPublished - 2024

Bibliographical note

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 899528 (ITS-THIN).

Keywords

  • Forward osmosis
  • Defected area
  • Pore support structure
  • ICP
  • Pore shape geometry
  • Cross-flow velocity
  • Computational fluid dynamics
  • Tortuosity

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