Influence of hydroxyl content of binders on rheological properties of cerium-gadolinium oxide (CGO) screen printing inks

Debora Marani, Christophe Gadea, Johan Hjelm, Per Hjalmarsson, Marie Wandel, Wolff-Ragnar Kiebach

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

The influence of hydroxyl content of binders on rheological properties of screen printing inks is investigated. The actual amount of hydroxyl groups is correlated to the level of hyper-entanglement that characterizes the binders in solution. Three of the most used binders (ethyl cellulose, and two vinyl resins) were selected and characterized in solution via viscosimetry method. A high degree of hyper-entanglement was observed for ethyl cellulose polymers, whereas a mitigated effect characterized the two vinyl resins. Cerium-gadolinium oxides (CGO)-based inks, prepared using the selected binders, were investigated by means of rheology. The vinyl resin at higher hydroxyl content and low level of hyper-entanglement was demonstrated to impart superior printability properties.
Original languageEnglish
JournalJournal of the European Ceramic Society
Volume35
Issue number5
Pages (from-to)1495–1504
Number of pages10
ISSN0955-2219
DOIs
Publication statusPublished - 2015

Keywords

  • Ceramic ink
  • Hyper-entanglement
  • Intrinsic viscosity
  • Rheology
  • Screen printing
  • Binders
  • Cellulose
  • Cerium
  • Elasticity
  • Gadolinium
  • Ink
  • Resins
  • Vinyl resins
  • Ethyl cellulose
  • Gadolinium oxide
  • Hydroxyl content
  • Hydroxyl groups
  • Rheological property
  • Viscosimetry

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