Improving the Operational Stability of PBDTTTz-4 Polymer Solar Cells Modules by Electrode Modification

Bérenger Roth; Gisele Alves dos Reis Benatto; Michael Corazza; Jon Eggert Carlé; Martin Helgesen; Suren Gevorgyan; Mikkel Jørgensen; Roar R. Søndergaard; Frederik C Krebs

doi:10.1002/adem.201500361

Improving the Operational Stability of PBDTTTz-4 Polymer Solar Cells Modules by Electrode Modification

Bérenger Roth, Gisele Alves dos Reis Benatto, Michael Corazza, Jon Eggert Carlé, Martin Helgesen, Suren Gevorgyan, Mikkel Jørgensen, Roar R. Søndergaard, Frederik C Krebs

Department of Energy Conversion and Storage

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

PBDTTTz-4 is employed in the ambient manufacturing of fully Roll-to-Roll organic solar cell modules. Modules are manufactured using a novel silver nanowire electrode or a previously reported carbon electrode. The average PCE of carbon modules (3.07%) and AgNW modules (1.46%) shows that PBDTTTz-4 is a good candidate for upscaling. Stability measurements following the ISOS standards are used to compare the lifetime of the different modules. In all tests but one, the carbon modules are less stable. The higher stability of AgNW is attributed to the removal of the PEDOT:PSS in the front electrode. Finally during indoor light tests, a new degradation phenomenon is observed where bubbles are formed inside the modules contrary to previous reports of bubble formation by thermal expansion of trapped gas inside the barrier.

Original language	English
Journal	Advanced Engineering Materials
Volume	18
Issue number	4
Pages (from-to)	511-517
Number of pages	7
ISSN	1438-1656
DOIs	https://doi.org/10.1002/adem.201500361
Publication status	Published - 2016

Bibliographical note

This work has been supported by the Eurotech Universities Alliance project “Interface science for photovoltaics (ISPV)”

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title = "Improving the Operational Stability of PBDTTTz-4 Polymer Solar Cells Modules by Electrode Modification",

abstract = "PBDTTTz-4 is employed in the ambient manufacturing of fully Roll-to-Roll organic solar cell modules. Modules are manufactured using a novel silver nanowire electrode or a previously reported carbon electrode. The average PCE of carbon modules (3.07%) and AgNW modules (1.46%) shows that PBDTTTz-4 is a good candidate for upscaling. Stability measurements following the ISOS standards are used to compare the lifetime of the different modules. In all tests but one, the carbon modules are less stable. The higher stability of AgNW is attributed to the removal of the PEDOT:PSS in the front electrode. Finally during indoor light tests, a new degradation phenomenon is observed where bubbles are formed inside the modules contrary to previous reports of bubble formation by thermal expansion of trapped gas inside the barrier.",

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year = "2016",

doi = "10.1002/adem.201500361",

language = "English",

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AU - Roth, Bérenger

AU - Benatto, Gisele Alves dos Reis

AU - Corazza, Michael

AU - Carlé, Jon Eggert

AU - Helgesen, Martin

AU - Gevorgyan, Suren

AU - Jørgensen, Mikkel

AU - Søndergaard, Roar R.

AU - Krebs, Frederik C

N1 - This work has been supported by the Eurotech Universities Alliance project “Interface science for photovoltaics (ISPV)”

PY - 2016

Y1 - 2016

N2 - PBDTTTz-4 is employed in the ambient manufacturing of fully Roll-to-Roll organic solar cell modules. Modules are manufactured using a novel silver nanowire electrode or a previously reported carbon electrode. The average PCE of carbon modules (3.07%) and AgNW modules (1.46%) shows that PBDTTTz-4 is a good candidate for upscaling. Stability measurements following the ISOS standards are used to compare the lifetime of the different modules. In all tests but one, the carbon modules are less stable. The higher stability of AgNW is attributed to the removal of the PEDOT:PSS in the front electrode. Finally during indoor light tests, a new degradation phenomenon is observed where bubbles are formed inside the modules contrary to previous reports of bubble formation by thermal expansion of trapped gas inside the barrier.

AB - PBDTTTz-4 is employed in the ambient manufacturing of fully Roll-to-Roll organic solar cell modules. Modules are manufactured using a novel silver nanowire electrode or a previously reported carbon electrode. The average PCE of carbon modules (3.07%) and AgNW modules (1.46%) shows that PBDTTTz-4 is a good candidate for upscaling. Stability measurements following the ISOS standards are used to compare the lifetime of the different modules. In all tests but one, the carbon modules are less stable. The higher stability of AgNW is attributed to the removal of the PEDOT:PSS in the front electrode. Finally during indoor light tests, a new degradation phenomenon is observed where bubbles are formed inside the modules contrary to previous reports of bubble formation by thermal expansion of trapped gas inside the barrier.

U2 - 10.1002/adem.201500361

DO - 10.1002/adem.201500361

M3 - Journal article

VL - 18

SP - 511

EP - 517

JO - Advanced Engineering Materials

JF - Advanced Engineering Materials

SN - 1438-1656

IS - 4

ER -

Improving the Operational Stability of PBDTTTz-4 Polymer Solar Cells Modules by Electrode Modification

Abstract

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