Impedance Spectroscopy and Catalytic Activity Characterization of a La0.85Sr0.15MnO3/Ce0.9Gd0.1O1.95 Electrochemical Reactor for the Oxidation of Propene

Davide Ippolito, Kent Kammer Hansen

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

This study aims to characterize the catalytic and electrochemical behavior of a La0.85Sr0.15MnO3/Ce0.9Gd0.1O1.95 porous reactor for the oxidation of propene in the presence of oxygen. The application of anodic polarization strongly increased the propene oxidation rate up to 71 %, although the current efficiency remained low. The effect of prolonged polarization on the reactor catalytic activity was evaluated. Prolonged polarization enhanced both the reactor intrinsic catalytic activity and the electrode performance due to the formation of oxygen vacancies on the electrode surface. Electrochemical impedance spectroscopy was used to investigate the effect of propene introduction on the reactor impedance response. The introduction of propene into reactive system caused a strong increase of electrode resistance, mainly located in the low-frequency region of the impedance spectrum. This effect was caused by the strong adsorption of propene on electrode surfaces inhibiting the adsorption and dissociation of oxygen.
Original languageEnglish
JournalElectrocatalysis
Volume5
Issue number4
Pages (from-to)419-425
Number of pages7
ISSN1868-2529
DOIs
Publication statusPublished - 2014

Keywords

  • CHEMISTRY,
  • ELECTROCHEMISTRY
  • DEEP OXIDATION
  • PROMOTION
  • ELECTRODE
  • OXYGEN
  • KINETICS
  • PROPANE
  • TOLUENE
  • CELLS
  • LSM
  • GDC
  • Propene oxidation
  • Impedance spectroscopy
  • Electrochemical membrane reactor
  • HASH(0x56e2cd8)

Cite this

@article{44348c7190854895ab7b134afa25d5c0,
title = "Impedance Spectroscopy and Catalytic Activity Characterization of a La0.85Sr0.15MnO3/Ce0.9Gd0.1O1.95 Electrochemical Reactor for the Oxidation of Propene",
abstract = "This study aims to characterize the catalytic and electrochemical behavior of a La0.85Sr0.15MnO3/Ce0.9Gd0.1O1.95 porous reactor for the oxidation of propene in the presence of oxygen. The application of anodic polarization strongly increased the propene oxidation rate up to 71 {\%}, although the current efficiency remained low. The effect of prolonged polarization on the reactor catalytic activity was evaluated. Prolonged polarization enhanced both the reactor intrinsic catalytic activity and the electrode performance due to the formation of oxygen vacancies on the electrode surface. Electrochemical impedance spectroscopy was used to investigate the effect of propene introduction on the reactor impedance response. The introduction of propene into reactive system caused a strong increase of electrode resistance, mainly located in the low-frequency region of the impedance spectrum. This effect was caused by the strong adsorption of propene on electrode surfaces inhibiting the adsorption and dissociation of oxygen.",
keywords = "CHEMISTRY,, ELECTROCHEMISTRY, DEEP OXIDATION, PROMOTION, ELECTRODE, OXYGEN, KINETICS, PROPANE, TOLUENE, CELLS, LSM, GDC, Propene oxidation, Impedance spectroscopy, Electrochemical membrane reactor, HASH(0x56e2cd8)",
author = "Davide Ippolito and {Kammer Hansen}, Kent",
year = "2014",
doi = "10.1007/s12678-014-0210-5",
language = "English",
volume = "5",
pages = "419--425",
journal = "Electrocatalysis",
issn = "1868-2529",
publisher = "Springer New York",
number = "4",

}

Impedance Spectroscopy and Catalytic Activity Characterization of a La0.85Sr0.15MnO3/Ce0.9Gd0.1O1.95 Electrochemical Reactor for the Oxidation of Propene. / Ippolito, Davide; Kammer Hansen, Kent.

In: Electrocatalysis, Vol. 5, No. 4, 2014, p. 419-425.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Impedance Spectroscopy and Catalytic Activity Characterization of a La0.85Sr0.15MnO3/Ce0.9Gd0.1O1.95 Electrochemical Reactor for the Oxidation of Propene

AU - Ippolito, Davide

AU - Kammer Hansen, Kent

PY - 2014

Y1 - 2014

N2 - This study aims to characterize the catalytic and electrochemical behavior of a La0.85Sr0.15MnO3/Ce0.9Gd0.1O1.95 porous reactor for the oxidation of propene in the presence of oxygen. The application of anodic polarization strongly increased the propene oxidation rate up to 71 %, although the current efficiency remained low. The effect of prolonged polarization on the reactor catalytic activity was evaluated. Prolonged polarization enhanced both the reactor intrinsic catalytic activity and the electrode performance due to the formation of oxygen vacancies on the electrode surface. Electrochemical impedance spectroscopy was used to investigate the effect of propene introduction on the reactor impedance response. The introduction of propene into reactive system caused a strong increase of electrode resistance, mainly located in the low-frequency region of the impedance spectrum. This effect was caused by the strong adsorption of propene on electrode surfaces inhibiting the adsorption and dissociation of oxygen.

AB - This study aims to characterize the catalytic and electrochemical behavior of a La0.85Sr0.15MnO3/Ce0.9Gd0.1O1.95 porous reactor for the oxidation of propene in the presence of oxygen. The application of anodic polarization strongly increased the propene oxidation rate up to 71 %, although the current efficiency remained low. The effect of prolonged polarization on the reactor catalytic activity was evaluated. Prolonged polarization enhanced both the reactor intrinsic catalytic activity and the electrode performance due to the formation of oxygen vacancies on the electrode surface. Electrochemical impedance spectroscopy was used to investigate the effect of propene introduction on the reactor impedance response. The introduction of propene into reactive system caused a strong increase of electrode resistance, mainly located in the low-frequency region of the impedance spectrum. This effect was caused by the strong adsorption of propene on electrode surfaces inhibiting the adsorption and dissociation of oxygen.

KW - CHEMISTRY,

KW - ELECTROCHEMISTRY

KW - DEEP OXIDATION

KW - PROMOTION

KW - ELECTRODE

KW - OXYGEN

KW - KINETICS

KW - PROPANE

KW - TOLUENE

KW - CELLS

KW - LSM

KW - GDC

KW - Propene oxidation

KW - Impedance spectroscopy

KW - Electrochemical membrane reactor

KW - HASH(0x56e2cd8)

U2 - 10.1007/s12678-014-0210-5

DO - 10.1007/s12678-014-0210-5

M3 - Journal article

VL - 5

SP - 419

EP - 425

JO - Electrocatalysis

JF - Electrocatalysis

SN - 1868-2529

IS - 4

ER -