Impact of Variable Water Chemistry on PFOS-Goethite Interactions: Experimental Evidence and Surface Complexation Modeling

Perfluorooctanesulfonate (PFOS) has become a major concern due to its widespread occurrence in the environment and severe toxic effects. In this study, we investigate PFOS sorption on goethite surfaces under different water chemistry conditions to understand the impact of variable groundwater chemistry. Our investigation is based on multiple lines of evidence, including (i) a series of sorption experiments with varying pH, ionic strength, and PFOS initial concentration, (ii) IR spectroscopy analysis, and (iii) surface complexation modeling. PFOS was found to bind to goethite through a strong hydrogen-bonded (HB) complex and a weaker outer-sphere complex involving Na⁺ coadsorption (OS-Na⁺). The pH and ionic strength of the solution had a nontrivial impact on the speciation and coexistence of these surface complexes. Acidic conditions and low ionic strength promoted hydrogen bonding between the sulfonate headgroup and protonated hydroxo surface sites. Higher electrolyte concentrations and pH values hindered the formation of strong hydrogen bonds upon the formation of a ternary PFOS-Na⁺-goethite outer-sphere complex. The findings of this study illuminate the key control of variable solution chemistry on PFOS adsorption to mineral surfaces and the importance to develop surface complexation models integrating mechanistic insights for the accurate prediction of PFOS mobility and environmental fate.