Hysteresis Phenomena in Sulfur Dioxide Oxidation over
                Supported Vanadium Catalysts

Stephen G. Masters; Kim Michael Eriksen; Rasmus Fehrmann

Hysteresis Phenomena in Sulfur Dioxide Oxidation over Supported Vanadium Catalysts

Stephen G. Masters, Kim Michael Eriksen, Rasmus Fehrmann

Department of Chemistry

Imperial College London

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Catalyst deactivation and hysteresis behavior in industrial SO2-oxidation catalysts have been studied in the temperature region 350-480 C by combined in situ EPR spectroscopy and catalytic activity measurements. The feed gas composition simulated sulfuric acid synthesis gas and wet/dry deNOx'ed flue gas. The vanadium (IV) compound K4(VO)3(SO4)5 precipitated during all the investigated conditions hence causing catalyst deactivation. Hysteresis behavior of both the catalytic activity and the V(IV) content was observed during reheating.

Original language	English
Journal	J. Molec. Catal.
Volume	A
Issue number	120
Pages (from-to)	227-233
Publication status	Published - 1997

OpenUrl availability

Full text

Cite this

@article{31209a12451d492cad8563bbf08bcaac,

title = "Hysteresis Phenomena in Sulfur Dioxide Oxidation over Supported Vanadium Catalysts",

abstract = "Catalyst deactivation and hysteresis behavior in industrial SO2-oxidation catalysts have been studied in the temperature region 350-480 C by combined in situ EPR spectroscopy and catalytic activity measurements. The feed gas composition simulated sulfuric acid synthesis gas and wet/dry deNOx'ed flue gas. The vanadium (IV) compound K4(VO)3(SO4)5 precipitated during all the investigated conditions hence causing catalyst deactivation. Hysteresis behavior of both the catalytic activity and the V(IV) content was observed during reheating.",

author = "Masters, {Stephen G.} and Eriksen, {Kim Michael} and Rasmus Fehrmann",

year = "1997",

language = "English",

volume = "A",

pages = "227--233",

journal = "J. Molec. Catal.",

number = "120",

}

TY - JOUR

T1 - Hysteresis Phenomena in Sulfur Dioxide Oxidation over Supported Vanadium Catalysts

AU - Masters, Stephen G.

AU - Eriksen, Kim Michael

AU - Fehrmann, Rasmus

PY - 1997

Y1 - 1997

N2 - Catalyst deactivation and hysteresis behavior in industrial SO2-oxidation catalysts have been studied in the temperature region 350-480 C by combined in situ EPR spectroscopy and catalytic activity measurements. The feed gas composition simulated sulfuric acid synthesis gas and wet/dry deNOx'ed flue gas. The vanadium (IV) compound K4(VO)3(SO4)5 precipitated during all the investigated conditions hence causing catalyst deactivation. Hysteresis behavior of both the catalytic activity and the V(IV) content was observed during reheating.

AB - Catalyst deactivation and hysteresis behavior in industrial SO2-oxidation catalysts have been studied in the temperature region 350-480 C by combined in situ EPR spectroscopy and catalytic activity measurements. The feed gas composition simulated sulfuric acid synthesis gas and wet/dry deNOx'ed flue gas. The vanadium (IV) compound K4(VO)3(SO4)5 precipitated during all the investigated conditions hence causing catalyst deactivation. Hysteresis behavior of both the catalytic activity and the V(IV) content was observed during reheating.

M3 - Journal article

VL - A

SP - 227

EP - 233

JO - J. Molec. Catal.

JF - J. Molec. Catal.

IS - 120

ER -