TY - JOUR
T1 - Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts
AU - Khokarale, Santosh Govind
AU - Garcia Suárez, Eduardo José
AU - Fehrmann, Rasmus
AU - Riisager, Anders
PY - 2017
Y1 - 2017
N2 - Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.
AB - Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.
U2 - 10.1002/cctc.201601428
DO - 10.1002/cctc.201601428
M3 - Journal article
SN - 1867-3880
VL - 9
JO - ChemCatChem
JF - ChemCatChem
ER -