Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts

Santosh Govind Khokarale; Eduardo José Garcia Suárez; Rasmus Fehrmann; Anders Riisager

doi:10.1002/cctc.201601428

Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts

Santosh Govind Khokarale, Eduardo José Garcia Suárez, Rasmus Fehrmann, Anders Riisager

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.

Original language	English
Journal	ChemCatChem
Volume	9
Number of pages	7
ISSN	1867-3880
DOIs	https://doi.org/10.1002/cctc.201601428
Publication status	Published - 2017

Access to Document

10.1002/cctc.201601428

Fingerprint Dive into the research topics of 'Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts'. Together they form a unique fingerprint.

Cite this

@article{8b713a42db4842cdb8f96dc4251a6ba7,

title = "Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts",

abstract = "Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.",

author = "Khokarale, {Santosh Govind} and {Garcia Su{\'a}rez}, {Eduardo Jos{\'e}} and Rasmus Fehrmann and Anders Riisager",

year = "2017",

doi = "10.1002/cctc.201601428",

language = "English",

volume = "9",

journal = "ChemCatChem",

issn = "1867-3880",

publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",

}

TY - JOUR

T1 - Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts

AU - Khokarale, Santosh Govind

AU - Garcia Suárez, Eduardo José

AU - Fehrmann, Rasmus

AU - Riisager, Anders

PY - 2017

Y1 - 2017

N2 - Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.

AB - Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.

U2 - 10.1002/cctc.201601428

DO - 10.1002/cctc.201601428

M3 - Journal article

VL - 9

JO - ChemCatChem

JF - ChemCatChem

SN - 1867-3880

ER -