Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts

Santosh Govind Khokarale; Eduardo José Garcia Suárez; Rasmus Fehrmann; Anders Riisager

doi:10.1002/cctc.201601428

Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts

Santosh Govind Khokarale, Eduardo José Garcia Suárez, Rasmus Fehrmann, Anders Riisager

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.

Original language	English
Journal	ChemCatChem
Volume	9
Number of pages	7
ISSN	1867-3880
DOIs	https://doi.org/10.1002/cctc.201601428
Publication status	Published - 2017

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10.1002/cctc.201601428

Cite this

Khokarale, S. G., Garcia Suárez, E. J., Fehrmann, R., & Riisager, A. (2017). Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts. ChemCatChem, 9. https://doi.org/10.1002/cctc.201601428

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abstract = "Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.",

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AU - Fehrmann, Rasmus

AU - Riisager, Anders

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AB - Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.

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