Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions

Jiwhan Kim, Chi-Woo Roh, Suman Kalyan Sahoo, Sungeun Yang, Junemin Bae, Jeong Woo Han, Hyunjoo Lee*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Single atomic Pt catalyst can offer efficient utilization of the expensive platinum and provide unique selectivity because it lacks ensemble sites. However, designing such a catalyst with high Pt loading and good durability is very challenging. Here, single atomic Pt catalyst supported on antimony-doped tin oxide (Pt1/ATO) is synthesized by conventional incipient wetness impregnation, with up to 8 wt% Pt. The single atomic Pt structure is confirmed by high-angle annular dark field scanning tunneling electron microscopy images and extended X-ray absorption fine structure analysis results. Density functional theory calculations show that replacing Sb sites with Pt atoms in the bulk phase or at the surface of SbSn or ATO is energetically favorable. The Pt1/ATO shows superior activity and durability for formic acid oxidation reaction, compared to a commercial Pt/C catalyst. The single atomic Pt structure is retained even after a harsh durability test, which is performed by repeating cyclic voltammetry in the range of 0.05–1.4 V for 1800 cycles. A full cell is fabricated for direct formic acid fuel cell using the Pt1/ATO as an anode catalyst, and an order of magnitude higher cell power is obtained compared to the Pt/C.
Original languageEnglish
Article number1701476
JournalAdvanced Energy Materials
Volume8
Issue number1
Number of pages8
ISSN1614-6832
DOIs
Publication statusPublished - 2018

Cite this

Kim, J., Roh, C-W., Sahoo, S. K., Yang, S., Bae, J., Han, J. W., & Lee, H. (2018). Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions. Advanced Energy Materials, 8(1), [1701476]. https://doi.org/10.1002/aenm.201701476
Kim, Jiwhan ; Roh, Chi-Woo ; Sahoo, Suman Kalyan ; Yang, Sungeun ; Bae, Junemin ; Han, Jeong Woo ; Lee, Hyunjoo. / Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions. In: Advanced Energy Materials. 2018 ; Vol. 8, No. 1.
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title = "Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions",
abstract = "Single atomic Pt catalyst can offer efficient utilization of the expensive platinum and provide unique selectivity because it lacks ensemble sites. However, designing such a catalyst with high Pt loading and good durability is very challenging. Here, single atomic Pt catalyst supported on antimony-doped tin oxide (Pt1/ATO) is synthesized by conventional incipient wetness impregnation, with up to 8 wt{\%} Pt. The single atomic Pt structure is confirmed by high-angle annular dark field scanning tunneling electron microscopy images and extended X-ray absorption fine structure analysis results. Density functional theory calculations show that replacing Sb sites with Pt atoms in the bulk phase or at the surface of SbSn or ATO is energetically favorable. The Pt1/ATO shows superior activity and durability for formic acid oxidation reaction, compared to a commercial Pt/C catalyst. The single atomic Pt structure is retained even after a harsh durability test, which is performed by repeating cyclic voltammetry in the range of 0.05–1.4 V for 1800 cycles. A full cell is fabricated for direct formic acid fuel cell using the Pt1/ATO as an anode catalyst, and an order of magnitude higher cell power is obtained compared to the Pt/C.",
author = "Jiwhan Kim and Chi-Woo Roh and Sahoo, {Suman Kalyan} and Sungeun Yang and Junemin Bae and Han, {Jeong Woo} and Hyunjoo Lee",
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Kim, J, Roh, C-W, Sahoo, SK, Yang, S, Bae, J, Han, JW & Lee, H 2018, 'Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions', Advanced Energy Materials, vol. 8, no. 1, 1701476. https://doi.org/10.1002/aenm.201701476

Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions. / Kim, Jiwhan; Roh, Chi-Woo; Sahoo, Suman Kalyan; Yang, Sungeun; Bae, Junemin; Han, Jeong Woo; Lee, Hyunjoo.

In: Advanced Energy Materials, Vol. 8, No. 1, 1701476, 2018.

Research output: Contribution to journalJournal articleResearchpeer-review

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T1 - Highly Durable Platinum Single-Atom Alloy Catalyst for Electrochemical Reactions

AU - Kim, Jiwhan

AU - Roh, Chi-Woo

AU - Sahoo, Suman Kalyan

AU - Yang, Sungeun

AU - Bae, Junemin

AU - Han, Jeong Woo

AU - Lee, Hyunjoo

PY - 2018

Y1 - 2018

N2 - Single atomic Pt catalyst can offer efficient utilization of the expensive platinum and provide unique selectivity because it lacks ensemble sites. However, designing such a catalyst with high Pt loading and good durability is very challenging. Here, single atomic Pt catalyst supported on antimony-doped tin oxide (Pt1/ATO) is synthesized by conventional incipient wetness impregnation, with up to 8 wt% Pt. The single atomic Pt structure is confirmed by high-angle annular dark field scanning tunneling electron microscopy images and extended X-ray absorption fine structure analysis results. Density functional theory calculations show that replacing Sb sites with Pt atoms in the bulk phase or at the surface of SbSn or ATO is energetically favorable. The Pt1/ATO shows superior activity and durability for formic acid oxidation reaction, compared to a commercial Pt/C catalyst. The single atomic Pt structure is retained even after a harsh durability test, which is performed by repeating cyclic voltammetry in the range of 0.05–1.4 V for 1800 cycles. A full cell is fabricated for direct formic acid fuel cell using the Pt1/ATO as an anode catalyst, and an order of magnitude higher cell power is obtained compared to the Pt/C.

AB - Single atomic Pt catalyst can offer efficient utilization of the expensive platinum and provide unique selectivity because it lacks ensemble sites. However, designing such a catalyst with high Pt loading and good durability is very challenging. Here, single atomic Pt catalyst supported on antimony-doped tin oxide (Pt1/ATO) is synthesized by conventional incipient wetness impregnation, with up to 8 wt% Pt. The single atomic Pt structure is confirmed by high-angle annular dark field scanning tunneling electron microscopy images and extended X-ray absorption fine structure analysis results. Density functional theory calculations show that replacing Sb sites with Pt atoms in the bulk phase or at the surface of SbSn or ATO is energetically favorable. The Pt1/ATO shows superior activity and durability for formic acid oxidation reaction, compared to a commercial Pt/C catalyst. The single atomic Pt structure is retained even after a harsh durability test, which is performed by repeating cyclic voltammetry in the range of 0.05–1.4 V for 1800 cycles. A full cell is fabricated for direct formic acid fuel cell using the Pt1/ATO as an anode catalyst, and an order of magnitude higher cell power is obtained compared to the Pt/C.

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