Higher-accuracy van der Waals density functional

Kyuho Lee, Éamonn D. Murray, Lingzhu Kong, Bengt Lundqvist, David C. Langreth

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We propose a second version of the van der Waals density functional of Dion et al. [Phys. Rev. Lett. 92, 246401 (2004)], employing a more accurate semilocal exchange functional and the use of a large-N asymptote gradient correction in determining the vdW kernel. The predicted binding energy, equilibrium separation, and potential-energy curve shape are close to those of accurate quantum chemical calculations on 22 duplexes. We anticipate the enabling of chemically accurate calculations in sparse materials of importance for condensed matter, surface, chemical, and biological physics.
Original languageEnglish
JournalPhysical Review B Condensed Matter
Issue number8
Pages (from-to)081101
Publication statusPublished - 2010

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Copyright 2010 American Physical Society


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